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Title: Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.

Abstract

This review presents a self-contained summary of the experimental methods necessary to perform a low temperature solid-state NMR experiment. Specific references are made for Zn²⁺ and Mg²⁺. However, this is not a comprehensive review of the NMR literature of these nuclides. As the review is concerned with solid-state NMR spectroscopy of quadrupolar nuclides, we limit the discussions to odd-half-integral spin systems, i.e. 3/2, 5/2, 7/2, and 9/2 spins. The reason for the limitation is due to the “relative ease” of observing the central transition, which is common to all of these nuclides. The review is divided into two major sections; the first dealing with experimental methods, e.g. use of low temperature, magnetization transfer, spin echo methods, and questions dealing with nonspecific binding. Following those discussions we turn to the introduction of structure into the experiment, i.e. the use triple resonance experiments to selectively introduce dipolar interactions and the use of molecular theory.

Authors:
;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
917216
Report Number(s):
PNWD-SA-6612
TRN: US200816%%348
DOE Contract Number:
AC05-76RL01830
Resource Type:
Book
Resource Relation:
Related Information: Annual Reports on NMR Spectroscopy, 60:1-38
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; NUCLEAR MAGNETIC RESONANCE; ZINC; MAGNESIUM; SPIN ECHO; MAGNETIZATION

Citation Formats

Ellis, Paul D., and Lipton, Andrew S. Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.. United States: N. p., 2007. Web.
Ellis, Paul D., & Lipton, Andrew S. Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.. United States.
Ellis, Paul D., and Lipton, Andrew S. Mon . "Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.". United States. doi:.
@article{osti_917216,
title = {Low Temperature Solid-State NMR Spectroscopy. A Strategy for the Direct Observation of Quadrupolar Nuclides of Biological Interest.},
author = {Ellis, Paul D. and Lipton, Andrew S.},
abstractNote = {This review presents a self-contained summary of the experimental methods necessary to perform a low temperature solid-state NMR experiment. Specific references are made for Zn²⁺ and Mg²⁺. However, this is not a comprehensive review of the NMR literature of these nuclides. As the review is concerned with solid-state NMR spectroscopy of quadrupolar nuclides, we limit the discussions to odd-half-integral spin systems, i.e. 3/2, 5/2, 7/2, and 9/2 spins. The reason for the limitation is due to the “relative ease” of observing the central transition, which is common to all of these nuclides. The review is divided into two major sections; the first dealing with experimental methods, e.g. use of low temperature, magnetization transfer, spin echo methods, and questions dealing with nonspecific binding. Following those discussions we turn to the introduction of structure into the experiment, i.e. the use triple resonance experiments to selectively introduce dipolar interactions and the use of molecular theory.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}

Book:
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