Electronic Excitations in Vanadium Oxide Phthalocyanine Studied via Resonant Soft X-ray Emission and Resonant Inelastic X-ray Scattering
Journal Article
·
· Chem. Phys. Lett.
The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 913691
- Report Number(s):
- BNL-78259-2007-JA; CHPLBC; TRN: US200804%%37
- Journal Information:
- Chem. Phys. Lett., Vol. 413, Issue 1-3; ISSN 0009-2614
- Country of Publication:
- United States
- Language:
- English
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