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Title: Erbium Implantation in Silica Studied by Molecular Dynamics Simulations

Abstract

Defect formation induced by erbium implantation in silica glass and cristobalite was studied using molecular dynamics simulations employing a partial charge model in combination with the ZBL potential. The results show that the number of displaced atoms generated at the same PKA energy is similar in silica and cristobalite but the number of coordination defects created is much lower in the cristobalite than in silica glass. In both cases, the erbium ion is able to create an optimal coordination environment at the end of the collision cascade. Subsequent thermal annealing causes the relaxation of the silicon oxygen network structure along with a reduction of silicon and oxygen defects. This research is supported by the Divisions of Materials Sciences and Engineering and Chemical Science, Office of Basic Energy Sciences, U.S. Department of Energy. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Authors:
;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
909460
Report Number(s):
PNNL-SA-52162
KC0301020; TRN: US0703891
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms, 255(1(SP ISS)):177-182; Journal Volume: 255; Journal Issue: 1(SP ISS)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; ANNEALING; ATOMS; CRISTOBALITE; DEFECTS; ERBIUM; ERBIUM IONS; GLASS; OXYGEN; RELAXATION; SILICA; SILICON; ion implantation; molecular dynamics simulation; glass; displacement cascades; optical materials

Citation Formats

Du, Jincheng, and Corrales, Louis R. Erbium Implantation in Silica Studied by Molecular Dynamics Simulations. United States: N. p., 2007. Web. doi:10.1016/j.nimb.2006.11.065.
Du, Jincheng, & Corrales, Louis R. Erbium Implantation in Silica Studied by Molecular Dynamics Simulations. United States. doi:10.1016/j.nimb.2006.11.065.
Du, Jincheng, and Corrales, Louis R. Thu . "Erbium Implantation in Silica Studied by Molecular Dynamics Simulations". United States. doi:10.1016/j.nimb.2006.11.065.
@article{osti_909460,
title = {Erbium Implantation in Silica Studied by Molecular Dynamics Simulations},
author = {Du, Jincheng and Corrales, Louis R.},
abstractNote = {Defect formation induced by erbium implantation in silica glass and cristobalite was studied using molecular dynamics simulations employing a partial charge model in combination with the ZBL potential. The results show that the number of displaced atoms generated at the same PKA energy is similar in silica and cristobalite but the number of coordination defects created is much lower in the cristobalite than in silica glass. In both cases, the erbium ion is able to create an optimal coordination environment at the end of the collision cascade. Subsequent thermal annealing causes the relaxation of the silicon oxygen network structure along with a reduction of silicon and oxygen defects. This research is supported by the Divisions of Materials Sciences and Engineering and Chemical Science, Office of Basic Energy Sciences, U.S. Department of Energy. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.},
doi = {10.1016/j.nimb.2006.11.065},
journal = {Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms, 255(1(SP ISS)):177-182},
number = 1(SP ISS),
volume = 255,
place = {United States},
year = {Thu Feb 01 00:00:00 EST 2007},
month = {Thu Feb 01 00:00:00 EST 2007}
}
  • Quasielastic neutron scattering (QENS) experiments carried out using time-of-flight and backscattering neutron spectrometers with widely different energy resolution and dynamic range revealed the diffusion dynamics of hydration water in nano-powder rutile (TiO2) and cassiterite (SnO2) that possess the rutile crystal structure with the (110) crystal face predominant on the surface. These isostructural oxides differ in their bulk dielectric constants, metal atom electronegativities, and lattice spacings, which may all contribute to differences in the structure and dynamics of sorbed water. When hydrated under ambient conditions, the nano-powders had similar levels of hydration: about 3.5 (OH/H2O) molecules per Ti2O4 surface structural unitmore » of TiO2 and about 4.0 (OH/H2O) molecules per Sn2O4 surface unit of SnO2. Ab initio-optimized classical molecular dynamics (MD) simulations of the (110) surfaces in contact with SPC/E water at these levels of hydration indicate three structurally-distinct sorbed water layers L1, L2, and L3, where the L1 species are either associated water molecules or dissociated hydroxyl groups in direct contact with the surface, L2 water molecules are hydrogen bonded to L1 and structural oxygen atoms at the surface, and L3 water molecules are more weakly bound. At the hydration levels studied, L3 is incomplete compared with axial oxygen density profiles of bulk SPC/E water in contact with these surfaces, but the structure and dynamics of L1 "L3 species are remarkably similar at full and reduced water coverage. Three hydration water diffusion components, on the time scale of a picosecond, tens of picoseconds, and a nanosecond could be extracted from the QENS spectra of both oxides. However, the spectral weight of the faster components was significantly lower for SnO2 compared to TiO2. In TiO2 hydration water, the more strongly bound L2 water molecules exhibited slow (on the time scale of a nanosecond) dynamics characterized by super-Arrhenius, fragile behavior above 220 K and the dynamic transition to Arrhenius, strong behavior at lower temperatures. The more loosely bound L3 water molecules in TiO2 exhibited faster dynamics with Arrhenius temperature dependence. On the other hand, the slow diffusion component in L2 hydration water on SnO2, also on the time scale of a nanosecond, showed little evidence of super-Arrhenius behavior or the fragile -to- strong transition. This observation demonstrates that the occurrence of super-Arrhenius dynamic behavior in surface water is sensitive to the strength of interaction of the water molecules with the surface and the distribution of surface water molecules among the different hydration layers. Analysis of energy transfer spectra generated from the molecular dynamics simulations shows fast and intermediate dynamics in good agreement with the QENS time-of-flight results. Also demonstrated by the simulation is the fast (compared to 1 ns) exchange between the water molecules of the L2 and L3 hydration layers.« less
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