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Title: JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution

Abstract

The Energy & Environmental Research Center (EERC) conducted remediation of hydrocarbon-contaminated soils and groundwater at a former Mohler Oil site in Bismarck, North Dakota. The remedial strategy was based on the application of two innovative concepts: (1) design and deployment of the mobile extraction, treatment, and injection units to overcome site limitations associated with urban settings in high-traffic areas and (2) vacuum-controlled nutrient injection within and on the periphery of an induced hydraulic and pneumatic depression. Combined contaminant recovery since the beginning of the project in June 2003 totals over 13,600 lb ({approx}6,170 kg) of hydrocarbons, equivalent to 2176 gallons (8236 l) of product. In situ delivery of 1504 Ib (682 kg) of ionic nitrate and 540 Ib (245 kg) of dissolved oxygen translates into further reduction of about 489 Ib (222 kg) of benzene for the same period and provides for long-term stimulation of the natural attenuation process. In addition to contaminant recovered by extraction and reduced by in situ biodegradation, a total of 4136 Ib (1876 kg) of oxygen was delivered to the saturated zone, resulting in further in situ reduction of an estimated 1324 lb (600 kg) of dissolved-phase hydrocarbons. Based on the results of the EERCmore » demonstration, the North Dakota Department of Health approved site abandonment and termination of the corrective action.« less

Authors:
Publication Date:
Research Org.:
University Of North Dakota
Sponsoring Org.:
USDOE
OSTI Identifier:
903316
DOE Contract Number:
FC26-98FT40321
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; BENZENE; BIODEGRADATION; DESIGN; DISTRIBUTION; HYDRAULICS; HYDROCARBONS; NATURAL ATTENUATION; NITRATES; NUTRIENTS; OXYGEN; PNEUMATICS; SOILS; STIMULATION; CONTAMINATION

Citation Formats

Jaroslav Solc. JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution. United States: N. p., 2007. Web. doi:10.2172/903316.
Jaroslav Solc. JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution. United States. doi:10.2172/903316.
Jaroslav Solc. Thu . "JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution". United States. doi:10.2172/903316. https://www.osti.gov/servlets/purl/903316.
@article{osti_903316,
title = {JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution},
author = {Jaroslav Solc},
abstractNote = {The Energy & Environmental Research Center (EERC) conducted remediation of hydrocarbon-contaminated soils and groundwater at a former Mohler Oil site in Bismarck, North Dakota. The remedial strategy was based on the application of two innovative concepts: (1) design and deployment of the mobile extraction, treatment, and injection units to overcome site limitations associated with urban settings in high-traffic areas and (2) vacuum-controlled nutrient injection within and on the periphery of an induced hydraulic and pneumatic depression. Combined contaminant recovery since the beginning of the project in June 2003 totals over 13,600 lb ({approx}6,170 kg) of hydrocarbons, equivalent to 2176 gallons (8236 l) of product. In situ delivery of 1504 Ib (682 kg) of ionic nitrate and 540 Ib (245 kg) of dissolved oxygen translates into further reduction of about 489 Ib (222 kg) of benzene for the same period and provides for long-term stimulation of the natural attenuation process. In addition to contaminant recovered by extraction and reduced by in situ biodegradation, a total of 4136 Ib (1876 kg) of oxygen was delivered to the saturated zone, resulting in further in situ reduction of an estimated 1324 lb (600 kg) of dissolved-phase hydrocarbons. Based on the results of the EERC demonstration, the North Dakota Department of Health approved site abandonment and termination of the corrective action.},
doi = {10.2172/903316},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Mar 15 00:00:00 EDT 2007},
month = {Thu Mar 15 00:00:00 EDT 2007}
}

Technical Report:

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  • The Energy and Environmental Research Center (EERC) conducted a demonstration of a vacuum-enhanced recovery and feasibility of permeable treatment barriers for soil and groundwater remediation at an Independent Oil (Former Star Mart) site in Hazen, North Dakota. A total of 62,584 lb (28,388) of contaminant was recovered from impacted soils and groundwater. The mass of recovered contaminant equals approximately 10,116 gallons of product. Groundwater quality monitoring confirmed the continuing contaminants of concern (COC) reduction trend in most monitoring wells and an average benzene reduction of 85% within the entire impacted area since remediation system start-up. A comparison of mass balancemore » estimates for the extraction system with biodegradation stoichiometry using the assimilative capacity of the groundwater indicates that in situ natural attenuation processes became a dominant factor in reducing COCs and that improved site conditions justified termination of corrective action. The unit cost of contaminant recovery was $15. 26/lb ($33.65/kg). If in situ degradation resulting from oxygen delivery is considered, the cost would be $12.62/b ($27.82/kg) of contaminant recovered or degraded.« less
  • The Energy & Environmental Research Center (EERC) conducted remediation of hydrocarbon-contaminated soils and groundwater at the Vining Oil site in Carrington, North Dakota. The primary technological synergies included (1) contaminant recovery using simultaneous operation of multiphase recovery and high-vacuum soil vapor extraction (SVE) and (2) vacuum-controlled air and ozone sparging on the periphery of an induced hydraulic and pneumatic depression. Final risk reduction steps included design and retrofit for the municipal well. The successful remediation effort resulted in the reduction of long-term health risks associated with rate-limited contaminant release within the capture zone for the municipal well and allowed formore » its reintegration into the water supply system. Contaminant recovery for the remediation period of September 2006 to June 2008 totaled over 12,653 lb (5,740 kg) of hydrocarbons, an equivalent to 2022 gallons (7653 l) of product. Integration of the air-sparging subsystem operated simultaneously with multiphase extraction and SVE systems resulted in accelerated volatile organic contaminant transport from the saturated zone and increased contaminants of concern recovery. Delivery of over 7.7 million ft{sup 3} of oxygen (219.8 thousand m{sup 3}) into the contaminated aquifer would translate into in situ biodegradation of 2007 kg (4424 lb) of benzene and provide for long term stimulation of the natural attenuation process.« less
  • The Energy & Environmental Research Center (EERC) conducted a limited site investigation and risk analyses for hydrocarbon-contaminated soils and groundwater at a Construction Services, Inc., site in Watford City, North Dakota. Site investigation confirmed the presence of free product and high concentrations of residual gasoline-based contaminants in several wells, the presence of 1,2-dichloroethane, and extremely high levels of electrical conductivity indicative of brine residuals in the tank area south of the facility. The risk analysis was based on compilation of information from the site-specific geotechnical investigation, including multiphase extraction pilot test, laser induced fluorescence probing, evaluation of contaminant properties, receptormore » survey, capture zone analysis and evaluation of well head protection area for municipal well field. The project results indicate that the risks associated with contaminant occurrence at the Construction Services, Inc. site are low and, under current conditions, there is no direct or indirect exposure pathway between the contaminated groundwater and soils and potential receptors.« less
  • Fine-textured soils and sediments contaminated by trichloroethylene (TCE) and other chlorinated organics present a serious environmental restoration challenge at US Department of Energy (DOE) sites. DOE and Martin Marietta Energy Systems, Inc. initiated a research and demonstration project at Oak Ridge National Laboratory. The goal of the project was to demonstrate a process for closure and environmental restoration of the X-231B Solid Waste Management Unit at the DOE Portsmouth Gaseous Diffusion Plant. The X-231B Unit was used from 1976 to 1983 as a land disposal site for waste oils and solvents. Silt and clay deposits beneath the unit were contaminatedmore » with volatile organic compounds and low levels of radioactive substances. The shallow groundwater was also contaminated, and some contaminants were at levels well above drinking water standards. This document begins with a summary of the subsurface physical and contaminant characteristics obtained from investigative studies conducted at the X-231B Unit prior to January 1992 (Sect. 2). This is then followed by a description of the sample collection and analysis methods used during the baseline sampling conducted in January 1992 (Sect. 3). The results of this sampling event were used to develop spatial models for VOC contaminant distribution within the X-231B Unit.« less
  • The objective of the Volatile Organic Compounds in Non-arid Soils Integrated Demonstration at the Savannah River Site is to evaluate innovative remediation, characterization, and monitoring systems to facilitate restoration of contaminated sites. The focus of the third phase of the Integrated Demonstration is to evaluate the use of heating technologies, both radio frequency and ohmic heating, to enhance the removal of contamination from clay layers. This report documents characterization data collected in support of the ohmic heating demonstration performed by researchers from PNL. The data presented and discussed in this report include a general description of the site including locationmore » of piezometers and sensors installed to monitor the remedial process, and detailed geologic cross sections of the study site, sampling and analysis procedures for sediment samples, tabulations of moisture and VOC content of the sediments, models of the distribution of contamination before and after the test, and a comparison of the volume estimations of contaminated material before and after the test. The results show that the heating process was successful in mobilizing and removing solvent from the heated interval.« less