skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands

Abstract

A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with -lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3)3(H2O). Battelle operates PNNL for the USDOE

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
903236
Report Number(s):
PNNL-SA-49118
KP1302000; TRN: US200719%%516
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Heterocyclic Chemistry, 44(1):99-103; Journal Volume: 44; Journal Issue: 1
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; PYRIDINES; OXIDES; SYNTHESIS; AMIDES; pyridines; pyridine N-oxides; propionamide; lanthanide ions; ligands; heterocycles

Citation Formats

Binyamin, Iris, Pailloux, Sylvie, Hay, Benjamin P, Rapko, Brian M, Duesler, Eileen N, and Paine, Robert T. Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands. United States: N. p., 2007. Web. doi:10.1002/jhet.5570440117.
Binyamin, Iris, Pailloux, Sylvie, Hay, Benjamin P, Rapko, Brian M, Duesler, Eileen N, & Paine, Robert T. Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands. United States. doi:10.1002/jhet.5570440117.
Binyamin, Iris, Pailloux, Sylvie, Hay, Benjamin P, Rapko, Brian M, Duesler, Eileen N, and Paine, Robert T. Thu . "Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands". United States. doi:10.1002/jhet.5570440117.
@article{osti_903236,
title = {Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands},
author = {Binyamin, Iris and Pailloux, Sylvie and Hay, Benjamin P and Rapko, Brian M and Duesler, Eileen N and Paine, Robert T},
abstractNote = {A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with -lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3)3(H2O). Battelle operates PNNL for the USDOE},
doi = {10.1002/jhet.5570440117},
journal = {Journal of Heterocyclic Chemistry, 44(1):99-103},
number = 1,
volume = 44,
place = {United States},
year = {Thu Feb 01 00:00:00 EST 2007},
month = {Thu Feb 01 00:00:00 EST 2007}
}