Alloy 22 Localized Corrosion Susceptibility In Aqueous Solutions Of Chloride And Nitrate Salts Of Sodium And Potassium At 110 - 150?C
Alloy 22 (a nickel-chromium-molybdenum-tungsten alloy) is being investigated for use as the outer barrier of waste containers for a high-level nuclear waste repository in the thick unsaturated zone at Yucca Mountain, Nevada. Experiments were conducted to assess crevice corrosion of Alloy 22 in de-aerated aqueous solutions of chloride and nitrate salts of potassium and sodium in the temperature range 110-150 C (some limited testing was also conducted at 90 C). Electrochemical tests were run in neutral salt solutions without acid addition and others were run in salt solutions with an initial hydrogen ion concentration of 10{sup -4} molal. The Alloy 22 specimens were weld prism specimens and de-aeration was performed with nitrogen gas. No evidence of crevice corrosion was observed in the range 125-150 C. In the 120 to 160 C temperature range, the anionic concentration of stable aqueous solutions is dominated by nitrate relative to chloride. At nominally 120 C, the minimum nitrate to chloride ratio is about 4.5, and it increases to about 22 at nominally 155 C. The absence of localized corrosion susceptibility in these solutions is attributed to the known inhibiting effect of the nitrate anion. At 110 C, aqueous solutions can have dissolved chloride in excess of nitrate. Localized corrosion was observed at nitrate to chloride ratios up to 1.0, the highest ratio tested. The extent of localized corrosion was confined to the crevice region of the samples, and was limited for nitrate to chloride ratios greater than or equal to 0.3. Aqueous solution chemistry studies indicate that nitrate to chloride ratios of less than 0.5 are possible for temperatures up to nominally 116 C. However, the exact upper temperature limit is unknown and no electrochemical testing was done at these temperatures. Limited comparison between 8 m Cl aqueous solutions of Na + K on the one hand and Ca on the other indicated similar electrochemical E{sub crit} values and similar morphology of attack, again limited to the crevice region. However, the 24 hr E{sub corr} value was higher for the Ca based solution; this is probably due to the higher acidity of this solution (Ca{sup 2+} is slightly hydrolyzing). Intermediate-term corrosion potential (E{sub corr}) measurements indicate that moderately acidic conditions are required to achieve elevated E{sub corr} values.
- Research Organization:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 893568
- Report Number(s):
- UCRL-TR-218195; TRN: US0606045
- Country of Publication:
- United States
- Language:
- English
Similar Records
Long Term Corrosion Potential and Corrosion Rate of Creviced Alloy 22 in Chloride Plus Nitrate Brines
Long Term Electrochemical Behavior of Creviced and Non-Creviced Alloy 22 in CaCl2 + Ca(NO3)2 Brines at 155?C
Related Subjects
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
36 MATERIALS SCIENCE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALLOYS
AQUEOUS SOLUTIONS
CHEMISTRY
CHLORIDES
CONTAINERS
CORROSION
CREVICE CORROSION
HYDROGEN IONS
MORPHOLOGY
NITRATES
NITROGEN
PH VALUE
POTASSIUM
PRISMS
RADIOACTIVE WASTES
SODIUM
TESTING
WASTES
YUCCA MOUNTAIN