Radiation-Induced Effects in Pyrochlore and Nanoscale Materials Engineering
Pyrochlore materials, A2B2O7, encompass a wide range of compositions and are technological important for energy and environment issues, for example, used as ionic conductor in solid oxide fuel cells and nuclear waste forms for the storage of actinides, particularly Pu. Here, the recent progresses in understanding ion beam irradiation-induced phenomena in pyrochlore compounds are briefly reviewed with the focus of ion beam-induced crystalline-to-amorphous and pyrochlore to fluorite structural transitions. Systematic ion irradiation studies of lanthanide pyrochlores in which B = Ti, Zr, and Sn have suggested that the radiation response of pyrochlore compounds is highly dependent on compositional changes. Both ionic size and the cation electronic configurations (e.g., bond-types) affect the structural distortion from the ideal fluorite structure and the response behavior of pyrochlore-structure types to ion beam irradiation. Ion beam-induced pyrochlore-to-fluorite structural transition occurs in all irradiated pyrochlore compositions, and the independent kinetics of cation and anion disordering processes were discussed. Numerous novel nanostructures have been created by utilizing the ion beam-induced amorphization, order-disorder transition and phase decomposition, such as amorphous and disordered nano-domains, perfectly latticed matched two-dimensional nanolayer, self-organized ripple structure, metallic nanoparticles and nanowires. The potential application of energetic particle irradiation for nano-engineering pyrochlore structured compounds is highlighted.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 889046
- Report Number(s):
- PNNL-SA-46336; 3448; KC0201020; TRN: US0604363
- Journal Information:
- Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms, 250(1-2):128-136, Vol. 250, Issue 1-2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
30 DIRECT ENERGY CONVERSION
ACTINIDES
ANIONS
CATIONS
FLUORITE
ION BEAMS
IRRADIATION
KINETICS
NANOSTRUCTURES
PYROCHLORE
RADIATIONS
RADIOACTIVE WASTES
RARE EARTHS
SOLID OXIDE FUEL CELLS
STORAGE
Radiation
pyrochlore
nanostructures
Environmental Molecular Sciences Laboratory