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Title: Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch

Abstract

The purpose of this plan is to provide a post-closure groundwater monitoring program for the 216-S-10 Pond and Ditch (S-10) treatment, storage, and/or disposal (TSD) unit. The plan incorporates the sum of knowledge about the potential for groundwater contamination to originate from the S-10, including groundwater monitoring results, hydrogeology, and operational history. The S-10 has not received liquid waste since October 1991. The closure of S-10 has been coordinated with the 200-CS-1 source operable unit in accordance with the Tri-Party Agreement interim milestones M-20-39 and M-15-39C. The S-10 is closely situated among other waste sites of very similar operational histories. The proximity of the S-10 to the other facilities (216-S-17 pond, 216-S-11 Pond, 216-S-5,6 cribs, 216-S-16 ditch and pond, and 216-U-9 ditch) indicate that at least some observed groundwater contamination beneath and downgradient of S-10 could have originated from waste sites other than S-10. Hence, it may not be feasible to strictly discriminate between the contributions of each waste site to groundwater contamination beneath the S-10. A post-closure groundwater monitoring network is proposed that will include the drilling of three new wells to replace wells that have gone dry. When completed, the revised network will meet the intent for groundwatermore » monitoring network under WAC 173-303-645, and enable an improved understanding of groundwater contamination at the S-10. Site-specific sampling constituents are based on the dangerous waste constituents of concern relating to RCRA TSD unit operations (TSD unit constituents) identified in the Part A Permit Application. Thus, a constituent is selected for monitoring if it is: A dangerous waste constituent identified in the Part A Permit Application, or A mobile decomposition product (i.e., nitrate from nitrite) of a Part A constituent, or A reliable indicator of the site-specific contaminants (i.e., specific conductance). Using these criteria, the following constituent list and sampling schedule is proposed: Constituent; Sampling Frequency Site-Specific Parameters; Hexavalent chromium (a); Semiannual Chloride; Semiannual Fluoride; Semiannual Nitrate; Semiannual Nitrite; Semiannual Specific conductance (field)(a); Semiannual Ancillary Parameters; Anions; Annual Alkalinity Annual Metals, (in addition to chromium); Annual pH (field) Semiannual Temperature (field); Semiannual Turbidity (field) Semiannual (a). These constituents will be subject to statistical tests after background is established. It will be necessary to install new monitoring wells and accumulate background data on the groundwater from those wells before statistical comparisons can be made. Until then, the constituents listed above will be evaluated by tracking and trending concentrations in all wells and comparing these results with the corresponding DWS or Hanford Site background concentration for each constituent. If a comparison value (background or DWS) for a constituent is exceeded, DOE will notify Ecology per WAC 173-303-645 (9) (g) requirements (within seven days or a time agreed to between DOE and Ecology).« less

Authors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
881940
Report Number(s):
PNNL-15731
830403000; TRN: US0603009
DOE Contract Number:
AC05-76RL01830
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; ACID NEUTRALIZING CAPACITY; CHROMIUM; LIQUID WASTES; MONITORING; NITRATES; SETTLING PONDS; TURBIDITY; GROUND WATER; GROUND DISPOSAL; CHLORIDES; FLUORIDES; NITRITES; HANFORD RESERVATION; 216-S-10; RCRA; Groundwater monitoring; post-closure

Citation Formats

Barnett, D BRENT., Williams, Bruce A., Chou, Charissa J., and Hartman, Mary J. Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch. United States: N. p., 2006. Web. doi:10.2172/881940.
Barnett, D BRENT., Williams, Bruce A., Chou, Charissa J., & Hartman, Mary J. Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch. United States. doi:10.2172/881940.
Barnett, D BRENT., Williams, Bruce A., Chou, Charissa J., and Hartman, Mary J. Fri . "Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch". United States. doi:10.2172/881940. https://www.osti.gov/servlets/purl/881940.
@article{osti_881940,
title = {Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch},
author = {Barnett, D BRENT. and Williams, Bruce A. and Chou, Charissa J. and Hartman, Mary J.},
abstractNote = {The purpose of this plan is to provide a post-closure groundwater monitoring program for the 216-S-10 Pond and Ditch (S-10) treatment, storage, and/or disposal (TSD) unit. The plan incorporates the sum of knowledge about the potential for groundwater contamination to originate from the S-10, including groundwater monitoring results, hydrogeology, and operational history. The S-10 has not received liquid waste since October 1991. The closure of S-10 has been coordinated with the 200-CS-1 source operable unit in accordance with the Tri-Party Agreement interim milestones M-20-39 and M-15-39C. The S-10 is closely situated among other waste sites of very similar operational histories. The proximity of the S-10 to the other facilities (216-S-17 pond, 216-S-11 Pond, 216-S-5,6 cribs, 216-S-16 ditch and pond, and 216-U-9 ditch) indicate that at least some observed groundwater contamination beneath and downgradient of S-10 could have originated from waste sites other than S-10. Hence, it may not be feasible to strictly discriminate between the contributions of each waste site to groundwater contamination beneath the S-10. A post-closure groundwater monitoring network is proposed that will include the drilling of three new wells to replace wells that have gone dry. When completed, the revised network will meet the intent for groundwater monitoring network under WAC 173-303-645, and enable an improved understanding of groundwater contamination at the S-10. Site-specific sampling constituents are based on the dangerous waste constituents of concern relating to RCRA TSD unit operations (TSD unit constituents) identified in the Part A Permit Application. Thus, a constituent is selected for monitoring if it is: A dangerous waste constituent identified in the Part A Permit Application, or A mobile decomposition product (i.e., nitrate from nitrite) of a Part A constituent, or A reliable indicator of the site-specific contaminants (i.e., specific conductance). Using these criteria, the following constituent list and sampling schedule is proposed: Constituent; Sampling Frequency Site-Specific Parameters; Hexavalent chromium (a); Semiannual Chloride; Semiannual Fluoride; Semiannual Nitrate; Semiannual Nitrite; Semiannual Specific conductance (field)(a); Semiannual Ancillary Parameters; Anions; Annual Alkalinity Annual Metals, (in addition to chromium); Annual pH (field) Semiannual Temperature (field); Semiannual Turbidity (field) Semiannual (a). These constituents will be subject to statistical tests after background is established. It will be necessary to install new monitoring wells and accumulate background data on the groundwater from those wells before statistical comparisons can be made. Until then, the constituents listed above will be evaluated by tracking and trending concentrations in all wells and comparing these results with the corresponding DWS or Hanford Site background concentration for each constituent. If a comparison value (background or DWS) for a constituent is exceeded, DOE will notify Ecology per WAC 173-303-645 (9) (g) requirements (within seven days or a time agreed to between DOE and Ecology).},
doi = {10.2172/881940},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Mar 17 00:00:00 EST 2006},
month = {Fri Mar 17 00:00:00 EST 2006}
}

Technical Report:

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  • This ICN updates the groundwater monitoring plan. The list of constituents and the frequency of sampling is updated to reflect current needs and updates the list of wells within the network.
  • During 2003, the upgradient well 299-W26-7 went dry and one new groundwater monitoring well was installed downgradient (well 299-W26-14) of the 216-S-10 pond and ditch. This ICN updates the groundwater monitoring wells for the 216-S-10 pond and ditch and adds a revised well location map to the plan.
  • This report describes a groundwater monitoring plan for the 216-S-10 pond and ditch on the Hanford Site. This plan complies with the requirements of RCRA, CERCLA, and 40 CFR 265. This plan provides DOE with a revised detection monitoring well network and updates the list of constituents based on the knowledge gained from data collected over the years.
  • This document presents a groundwater quality assessment monitoring plan, under Resource Conservation and Recovery Act of 1976 (RCRA) regulatory requirements for three RCRA sites in the Hanford Site`s 200 East Area: 216-A-10, 216-A-36B, and 216-A-37-1 cribs (PUREX cribs). The objectives of this monitoring plan are to combine the three facilities into one groundwater quality assessment program and to assess the nature, extent, and rate of contaminant migration from these facilities. A groundwater quality assessment plan is proposed because at least one downgradient well in the existing monitoring well networks has concentrations of groundwater constituents indicating that the facilities have contributedmore » to groundwater contamination. The proposed combined groundwater monitoring well network includes 11 existing near-field wells to monitor contamination in the aquifer in the immediate vicinity of the PUREX cribs. Because groundwater contamination from these cribs is known to have migrated as far away as the 300 Area (more than 25 km from the PUREX cribs), the plan proposes to use results of groundwater analyses from 57 additional wells monitored to meet environmental monitoring requirements of US Department of Energy Order 5400.1 to supplement the near-field data. Assessments of data collected from these wells will help with a future decision of whether additional wells are needed.« less