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Title: Micro-Machined Thin Film Sensor Arrays For The Detection Of H2, Containing Gases, And Method Of Making And Using The Same.

Patent ·
OSTI ID:880423

The present invention provides a hydrogen sensor including a thin film sensor element formed by metal organic chemical vapor deposition (MOCVD) or physical vapor deposition (PVD), on a micro-hotplate structure. The thin film sensor element includes a film of a hydrogen-interactive metal film that reversibly interacts with hydrogen to provide a correspondingly altered response characteristic, such as optical transmissivity, electrical conductance, electrical resistance, electrical capacitance, magneto resistance, photoconductivity, etc., relative to the response characteristic of the film in the absence of hydrogen. The hydrogen-interactive metal film may be overcoated with a thin film hydrogen-permeable barrier layer to protect the hydrogen-interactive film from deleterious interaction with non-hydrogen species. The hydrogen permeable barrier may comprise species to scavenge oxygen and other like species. The hydrogen sensor of the invention may be usefully employed for the detection of hydrogen in an environment susceptible to the incursion or generation of hydrogen and may be conveniently configured as a hand-held apparatus.

Research Organization:
Advanced Technology Materials, Inc. (Danbury, CT)
DOE Contract Number:
FC36-99GO10451
Assignee:
Advanced Technology Materials, Inc. (Danbury, CT)
Patent Number(s):
US 6596236
Application Number:
10/828115
OSTI ID:
880423
Country of Publication:
United States
Language:
English

References (22)

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Visualization of hydrogen migration in solids using switchable mirrors journal August 1998
A micromachined ultra-thin-film gas detector journal January 1994
Silicon Microhotplate Arrays as a Platform for Efficient Gas Sensing Thin Film Research journal January 1996
Optical switches based on magnesium lanthanide alloy hydrides journal June 1997
In situ conductivity characterization of oxide thin film growth phenomena on microhotplates
  • DiMeo, F.; Cavicchi, R. E.; Semancik, S.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 16, Issue 1 https://doi.org/10.1116/1.580959
journal January 1998
Polymer film-based sensors for ammonia detection journal March 1992
Tin oxide gas sensor fabricated using CMOS micro-hotplates and in-situ processing journal March 1993
The room temperature ammonia sensor based on improved CuxS-micro-porous-Si structure journal August 2001
Monolithic thin-film metal-oxide gas-sensor arrays with application to monitoring of organic vapors journal July 1995
Microelectronic manufacturing of a microsensor based on polyaniline for ammonia gas sensing conference January 1999
Logarithmic Divergence of the Electrical Resistivity in the Metal Hydride YH 3 δ journal November 1997
Fast temperature programmed sensing for micro-hotplate gas sensors journal June 1995
On the semiconducting state and structural properties of YH3 from first principles theory journal December 1997
Selected-area deposition of multiple active films for conductometric microsensor arrays journal August 1996
Yttrium and lanthanum hydride films with switchable optical properties journal March 1996
A selected-area CVD method for deposition of sensing films on monolithically integrated gas detectors journal June 1995
Growth of SnO 2 films on micromachined hotplates journal February 1995
MOCVD OF SnO 2 on Silicon Microhotplate Arrays for use un Gas Sensing Applications journal January 1995

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