The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol
Abstract
Far-infrared absorption spectroscopy is used to investigate the low frequency ({center_dot} 100 cm{sup -1}) intermolecular interactions in liquid methanol. Using an intense source of far-infrared radiation, modes are elucidated at approximately 30 cm{sup -1} and 70 cm{sup -1} in the absorption spectrum. These modes are believed to arise from intermolecular bending and librational motions respectively and are successfully reproduced in an ab initio molecular dynamics simulation of methanol.
- Authors:
- Publication Date:
- Research Org.:
- Stanford Linear Accelerator Center (SLAC)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 878852
- Report Number(s):
- SLAC-PUB-11337
TRN: US200612%%185
- DOE Contract Number:
- AC02-76SF00515
- Resource Type:
- Technical Report
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 10 SYNTHETIC FUELS; ABSORPTION; ABSORPTION SPECTROSCOPY; BENDING; CHAINS; METHANOL; SIMULATION; Other,ACCPHY, BIO, CHEM, MATSCI
Citation Formats
Woods, K N, /Stanford U., Phys. Dept., Wiedemann, H, and /SLAC, SSRL. The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol. United States: N. p., 2005.
Web. doi:10.2172/878852.
Woods, K N, /Stanford U., Phys. Dept., Wiedemann, H, & /SLAC, SSRL. The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol. United States. https://doi.org/10.2172/878852
Woods, K N, /Stanford U., Phys. Dept., Wiedemann, H, and /SLAC, SSRL. Mon .
"The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol". United States. https://doi.org/10.2172/878852. https://www.osti.gov/servlets/purl/878852.
@article{osti_878852,
title = {The Influence of Chain Dynamics on theFar-Infrared Spectrum of Liquid Methanol},
author = {Woods, K N and /Stanford U., Phys. Dept. and Wiedemann, H and /SLAC, SSRL},
abstractNote = {Far-infrared absorption spectroscopy is used to investigate the low frequency ({center_dot} 100 cm{sup -1}) intermolecular interactions in liquid methanol. Using an intense source of far-infrared radiation, modes are elucidated at approximately 30 cm{sup -1} and 70 cm{sup -1} in the absorption spectrum. These modes are believed to arise from intermolecular bending and librational motions respectively and are successfully reproduced in an ab initio molecular dynamics simulation of methanol.},
doi = {10.2172/878852},
url = {https://www.osti.gov/biblio/878852},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2005},
month = {7}
}
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