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Title: Behavior of Np(VII, VI, V) in Silicate Solutions

Abstract

Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not possible using similar methods.

Authors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
878284
Report Number(s):
PNNL-SA-43277
Journal ID: ISSN 0033-8311; RADKAU; TRN: US0602267
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Radiokhimiya; Journal Volume: 46; Journal Issue: 6
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NEPTUNIUM COMPOUNDS; SPECTROPHOTOMETRY; SILICATES; CARBONATES; NEPTUNIUM COMPLEXES; STABILITY

Citation Formats

Shilov, V P., Fedoseev, A M., Yusov, A B., and Delegard, Calvin H. Behavior of Np(VII, VI, V) in Silicate Solutions. United States: N. p., 2004. Web. doi:10.1007/s11137-005-0030-9.
Shilov, V P., Fedoseev, A M., Yusov, A B., & Delegard, Calvin H. Behavior of Np(VII, VI, V) in Silicate Solutions. United States. doi:10.1007/s11137-005-0030-9.
Shilov, V P., Fedoseev, A M., Yusov, A B., and Delegard, Calvin H. Tue . "Behavior of Np(VII, VI, V) in Silicate Solutions". United States. doi:10.1007/s11137-005-0030-9.
@article{osti_878284,
title = {Behavior of Np(VII, VI, V) in Silicate Solutions},
author = {Shilov, V P. and Fedoseev, A M. and Yusov, A B. and Delegard, Calvin H.},
abstractNote = {Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not possible using similar methods.},
doi = {10.1007/s11137-005-0030-9},
journal = {Radiokhimiya},
number = 6,
volume = 46,
place = {United States},
year = {Tue Nov 30 00:00:00 EST 2004},
month = {Tue Nov 30 00:00:00 EST 2004}
}