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Title: Nuclear Energy Plant Optimization (NEPO) final report on aging and condition monitoring of low-voltage cable materials.

Technical Report ·
DOI:https://doi.org/10.2172/875986· OSTI ID:875986

This report summarizes results generated on a 5-year cable-aging program that constituted part of the Nuclear Energy Plant Optimization (NEPO) program, an effort cosponsored by the U. S. Department of Energy (DOE) and the Electric Power Research Institute (EPRI). The NEPO cable-aging effort concentrated on two important issues involving the development of better lifetime prediction methods as well as the development and testing of novel cable condition-monitoring (CM) techniques. To address improved life prediction methods, we first describe the use of time-temperature superposition principles, indicating how this approach improves the testing of the Arrhenius model by utilizing all of the experimentally generated data instead of a few selected and processed data points. Although reasonable superposition is often found, we show several cases where non-superposition is evident, a situation that violates the constant acceleration assumption normally used in accelerated aging studies. Long-term aging results over extended temperature ranges allow us to show that curvature in Arrhenius plots for elongation is a common occurrence. In all cases the curvature results in a lowering of the Arrhenius activation energy at lower temperatures implying that typical extrapolation of high temperature results over-estimates material lifetimes. The long-term results also allow us to test the significance of extrapolating through the crystalline melting point of semi-crystalline materials. By utilizing ultrasensitive oxygen consumption (UOC) measurements, we show that it is possible to probe the low temperature extrapolation region normally inaccessible to conventional accelerated aging studies. This allows the quantitative testing of the often-used Arrhenius extrapolation assumption. Such testing indicates that many materials again show evidence of ''downward'' curvature (E{sub a} values drop as the aging temperature is lowered) consistent with the limited elongation results and many literature results. It is also shown how the UOC approach allows the probing of temperatures that cross through the crystalline melting point region of semi-crystalline materials such as XLPO and EPR cable insulations. New results on combined environment aging of neoprene and hypalon cable jacketing materials are presented and offer additional evidence in support of our time-temperature-dose rate (t-T-DR) superposition approach that had been used successfully in the past for such situations.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
OSTI ID:
875986
Report Number(s):
SAND2005-7331; TRN: US0600932
Country of Publication:
United States
Language:
English