Adsorbent for metal ions and method of making and using
Patent
·
OSTI ID:872435
- Minneapolis, MN
- White Bear Township, MN
A method comprises the step of spray-drying a solution or slurry comprising (alkali metal or ammonium) (metal) hexacyanoferrate particles in a liquid, to provide monodisperse, substantially spherical particles in a yield of at least 70 percent of theoretical yield and having a particle size in the range of 1 to 500 micrometers, said particles being active towards Cs ions. The particles, which can be of a single salt or a combination of salts, can be used free flowing, in columns or beds, or entrapped in a nonwoven, fibrous web or matrix or a cast porous membrane, to selectively remove Cs ions from aqueous solutions.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC06-76RL01830; AR21-96MC33089
- Assignee:
- 3M Innovative Properties Company (St. Paul, MI)
- Patent Number(s):
- US 5935380
- OSTI ID:
- 872435
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
adsorbent
metal
method
comprises
step
spray-drying
solution
slurry
comprising
alkali
ammonium
hexacyanoferrate
particles
liquid
provide
monodisperse
substantially
spherical
yield
70
percent
theoretical
particle
size
range
500
micrometers
active
towards
cs
single
salt
combination
salts
free
flowing
columns
beds
entrapped
nonwoven
fibrous
web
matrix
cast
porous
membrane
selectively
remove
aqueous
solutions
slurry comprising
porous membrane
free flowing
spherical particles
method comprises
alkali metal
aqueous solution
particle size
aqueous solutions
substantially spherical
provide monodisperse
theoretical yield
active towards
method comprise
cast porous
selectively remove
free flow
fibrous web
hexacyanoferrate particles
spherical particle
/159/210/
metal
method
comprises
step
spray-drying
solution
slurry
comprising
alkali
ammonium
hexacyanoferrate
particles
liquid
provide
monodisperse
substantially
spherical
yield
70
percent
theoretical
particle
size
range
500
micrometers
active
towards
cs
single
salt
combination
salts
free
flowing
columns
beds
entrapped
nonwoven
fibrous
web
matrix
cast
porous
membrane
selectively
remove
aqueous
solutions
slurry comprising
porous membrane
free flowing
spherical particles
method comprises
alkali metal
aqueous solution
particle size
aqueous solutions
substantially spherical
provide monodisperse
theoretical yield
active towards
method comprise
cast porous
selectively remove
free flow
fibrous web
hexacyanoferrate particles
spherical particle
/159/210/