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Title: Process to convert biomass and refuse derived fuel to ethers and/or alcohols

Patent ·
OSTI ID:870364

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Research Organization:
Midwest Research Institute, Kansas City, MO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-83CH10093
Assignee:
Midwest Research Institute (Kansas City, MO)
Patent Number(s):
US 5504259
OSTI ID:
870364
Country of Publication:
United States
Language:
English

References (4)

Molecular Beam Mass Spectrometric Studies of HZSM-5 Activity During Wood Pyrolysis Product Conversion book January 1988
Low-Pressure Upgrading of Vacuum-Pyrolysis Oils from Wood book September 1988
Chemical and physical properties of the ZSM-5 substitutional series journal February 1980
The active site of acidic aluminosilicate catalysts journal June 1984