Use of aromatic salts for simultaneously removing SO.sub.2 and NO.sub.x pollutants from exhaust of a combustion system
Patent
·
OSTI ID:869525
- Boston, MA
- Belmont, MA
A method is disclosed for removing pollutants from the exhaust of combustion systems burning fuels containing substantial amounts of sulfur and nitrogen. An exemplary method of the invention involves the formation and reaction of a sorbent comprising calcium benzoate. The calcium benzoate is either dry-sprayed (in the form of a fine powder) or wet-sprayed in an aqueous solution in a high temperature environment such as a combustion chamber. The latter technique is feasible since calcium benzoate is a water-soluble form of calcium. When the dispersed particles of calcium benzoate are heated to a high temperature, the organic benzoate burns off and fine calcium oxide particles are formed. These particles are cenospheric (hollow) and have thin and highly porous walls, thus, affording optimum external and internal accessibility for reacting with toxic gaseous emissions such as SO.sub.2. Further, the combustion of the organic benzoate portion of the sorbent results in the conversion of NO.sub.x to N.sub.2.
- DOE Contract Number:
- ;
- Assignee:
- Northeastern University (Boston, MA)
- Patent Number(s):
- US 5352423
- Application Number:
- 08/039,853
- OSTI ID:
- 869525
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/423/
accessibility
affording
amounts
aqueous
aqueous solution
aromatic
benzoate
burning
burning fuels
burns
calcium
calcium oxide
cenospheric
chamber
combustion
combustion chamber
combustion systems
comprising
comprising calcium
containing
containing substantial
conversion
disclosed
dispersed
dispersed particles
dry-sprayed
emissions
environment
exemplary
exemplary method
exhaust
external
feasible
fine
fine calcium
fine powder
form
formation
formed
fuels
fuels containing
gaseous
gaseous emissions
heated
highly
highly porous
hollow
internal
involves
latter
method
nitrogen
optimum
organic
oxide
oxide particle
oxide particles
particles
pollutants
porous
porous wall
porous walls
portion
powder
reacting
reaction
removing
removing pollutants
results
salts
simultaneously
simultaneously removing
solution
sorbent
substantial
substantial amount
substantial amounts
sulfur
systems
systems burning
technique
temperature
temperature environment
toxic
toxic gas
walls
water-soluble
wet-sprayed
accessibility
affording
amounts
aqueous
aqueous solution
aromatic
benzoate
burning
burning fuels
burns
calcium
calcium oxide
cenospheric
chamber
combustion
combustion chamber
combustion systems
comprising
comprising calcium
containing
containing substantial
conversion
disclosed
dispersed
dispersed particles
dry-sprayed
emissions
environment
exemplary
exemplary method
exhaust
external
feasible
fine
fine calcium
fine powder
form
formation
formed
fuels
fuels containing
gaseous
gaseous emissions
heated
highly
highly porous
hollow
internal
involves
latter
method
nitrogen
optimum
organic
oxide
oxide particle
oxide particles
particles
pollutants
porous
porous wall
porous walls
portion
powder
reacting
reaction
removing
removing pollutants
results
salts
simultaneously
simultaneously removing
solution
sorbent
substantial
substantial amount
substantial amounts
sulfur
systems
systems burning
technique
temperature
temperature environment
toxic
toxic gas
walls
water-soluble
wet-sprayed