Method of forming a relatively stable slip of silicon metal particles and yttrium containing particles
Patent
·
OSTI ID:865158
- Birmingham, MI
- Flat Rock, MI
The method concerns forming a relatively stable slip of silicon metal particles and yttrium containing particles. In one embodiment, a casting slip of silicon metal particles is formed in water. Particles of a yttrium containing sintering aid are added to the casting slip. The yttrium containing sintering aid is a compound which has at least some solubility in water to form Y.sup.+3 ions which have a high potential for totally flocculating the silicon metal particles into a semiporous solid. A small amount of a fluoride salt is added to the casting slip which contains the yttrium containing sintering aid. The fluoride salt is one which will produce fluoride anions when dissolved in water. The small amount of the fluoride anions produced are effective to suppress the flocculation of the silicon metal particles by the Y.sup.+3 ions so that all particles remain in suspension in the casting slip and the casting slip has both an increased shelf life and can be used to cast articles having a relatively thick cross-section. The pH of the casting slip is maintained in a range from 7.5 to 9. Preferably, the fluoride salt used is one which is based on a monovalent cation such as sodium or ammonia. The steps of adding the yttrium containing sintering aid and the fluoride salt may be interchanged if desired, and the salt may be added to a solution containing the sintering aid prior to addition of the silicon metal particles.
- Assignee:
- Ford Motor Company (Dearborn, MI)
- Patent Number(s):
- US 4471060
- OSTI ID:
- 865158
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/501/264/
added
adding
addition
ammonia
amount
anions
articles
based
cast
cast article
casting
casting slip
cation
compound
concerns
containing
containing particles
contains
cross-section
desired
dissolved
effective
embodiment
flocculating
flocculation
fluoride
fluoride salt
form
formed
forming
increased
interchanged
life
maintained
metal
metal particle
metal particles
method
method concerns
monovalent
monovalent cation
particles
particles remain
ph
porous solid
potential
preferably
prior
produce
produced
range
relatively
relatively stable
relatively thick
remain
salt
semiporous
shelf
shelf life
silicon
silicon metal
sintering
slip
sodium
solid
solubility
solution
solution containing
stable
stable slip
steps
suppress
suspension
thick
totally
water
yttrium
yttrium containing
added
adding
addition
ammonia
amount
anions
articles
based
cast
cast article
casting
casting slip
cation
compound
concerns
containing
containing particles
contains
cross-section
desired
dissolved
effective
embodiment
flocculating
flocculation
fluoride
fluoride salt
form
formed
forming
increased
interchanged
life
maintained
metal
metal particle
metal particles
method
method concerns
monovalent
monovalent cation
particles
particles remain
ph
porous solid
potential
preferably
prior
produce
produced
range
relatively
relatively stable
relatively thick
remain
salt
semiporous
shelf
shelf life
silicon
silicon metal
sintering
slip
sodium
solid
solubility
solution
solution containing
stable
stable slip
steps
suppress
suspension
thick
totally
water
yttrium
yttrium containing