Origins of Deviations from Transition-State Theory: Formulating a New Kinetic Rate Law for Dissolution of Silicates
Present models for dissolution of silicate minerals and glasses, based on Transition-State Theory (TST), overestimate the reaction rate as solution compositions approach saturation with respect to the rate-governing solid.
- Research Organization:
- Rice Univ., Houston, TX (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG07-01ER63295
- OSTI ID:
- 861899
- Report Number(s):
- DOE/ER/63295; TRN: US200710%%61
- Country of Publication:
- United States
- Language:
- English
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