Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors

Patoux, Sebastien; Doeff, Marca M

doi:10.1016/j.elecom.2004.05.024

Title: Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors

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Abstract

Two novel methods for synthesis of the title compound directly from metal nitrates are described. Phase-pure materials are produced when precursors are calcined between 600 and 1000 C, with little to no ion mixing exhibited for products heated to 900 C or above. The electrochemical characteristics of these materials depended upon calcination temperature and synthesis method, with results comparable to a commercial sample for the materials made at high temperatures in a one-step process without combustion. The sample prepared by combustion also exhibited very stable capacity retention upon cycling.

Authors:: Patoux, Sebastien; Doeff, Marca M

Publication Date:: Wed Apr 28 00:00:00 EDT 2004

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE. Assistant Secretary for Energy Efficiency andRenewable Energy. Office of the FreedomCAR and Vehicle TechnologiesProgram

OSTI Identifier:: 860309

Report Number(s):: LBNL-54969
R&D Project: 500301; BnR: VT0301030; TRN: US200524%%83

DOE Contract Number:: DE-AC02-05CH11231

Resource Type:: Journal Article

Journal Name:: Electrochemistry Communications

Additional Journal Information:: Journal Volume: 6; Journal Issue: 8; Related Information: Journal Publication Date: 08/2004

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; CALCINATION; CAPACITY; COMBUSTION; NITRATES; RETENTION; SYNTHESIS

Citation Formats


                    Patoux, Sebastien, and Doeff, Marca M. Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors.  United States: N. p., 2004. 
        Web.  doi:10.1016/j.elecom.2004.05.024.

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                    Patoux, Sebastien, & Doeff, Marca M. Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors.  United States.  https://doi.org/10.1016/j.elecom.2004.05.024

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                    Patoux, Sebastien, and Doeff, Marca M. 2004.  
        "Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors".  United States.  https://doi.org/10.1016/j.elecom.2004.05.024.  https://www.osti.gov/servlets/purl/860309.

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@article{osti_860309,

  title        = {Direct synthesis of LiNi1/3Co1/3Mn1/3O2 from nitrateprecursors},

  author       = {Patoux, Sebastien and Doeff, Marca M},

  abstractNote = {Two novel methods for synthesis of the title compound directly from metal nitrates are described. Phase-pure materials are produced when precursors are calcined between 600 and 1000 C, with little to no ion mixing exhibited for products heated to 900 C or above. The electrochemical characteristics of these materials depended upon calcination temperature and synthesis method, with results comparable to a commercial sample for the materials made at high temperatures in a one-step process without combustion. The sample prepared by combustion also exhibited very stable capacity retention upon cycling.},

  doi          = {10.1016/j.elecom.2004.05.024},

  url          = {https://www.osti.gov/biblio/860309},
  journal      = {Electrochemistry Communications},
number       = 8,

  volume       = 6,

  place        = {United States},

  year         = {Wed Apr 28 00:00:00 EDT 2004},

  month        = {Wed Apr 28 00:00:00 EDT 2004}

}

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