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Title: SPECIATION, DISSOLUTION, AND REDOX REACTIONS OF CHROMIUM RELEVANT TO PRETREATMENT AND SEPARATION OF HIGH-LEVEL TANK WASTES

Abstract

Chromium, one of the problematic elements in tank sludges, is considered the most important constituent in defining the total volume of high-level radioactive waste (HLW) glass. Current sludge washing processes (e.g. caustic leaching, 3 M NaOH) are not effective in removing Cr. This inefficient removal would result in production of an unacceptably large volume of HLW glass and thus a tremendous increase in the cost of waste disposal. This proposed research seeks to develop fundamental data for chromium (Cr) reactions that are not currently available but are essential for developing effective methodologies for removing Cr form high-level waste (HLW). Our objectives are to study (1) the dissolution of several solid phases (e.g., CrOOH, Cr2O3(c), Cr(OH)3, and Fe and Cr, binary hydroxides, identified to be important from sludge leaching studies) in highly alkaline solutions and in the presence of other electrolytes (e.g., carbonate, phosphate, sulfate, nitrite), and (2) the effect of the nature of Cr solid phases and aqueous species on their redox reactivity with a variety of potential oxidants (e.g., H2O2, persulfate, O2, and ferrate). This information will provide critical support for developing enhanced pretreatment strategies for removing Cr from HLW and will achieve a major cost reduction in HLWmore » disposal.« less

Authors:
; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab., Richland, WA; Lawrence Berkeley National Lab., Berkeley, CA; Washington State University, Pullman, WA (US)
Sponsoring Org.:
USDOE Office of Science (SC) (US)
OSTI Identifier:
838639
Report Number(s):
EMSP-81896-2004
R&D Project: EMSP 81896; TRN: US0501479
DOE Contract Number:  
FG07-01ER14930
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 1 Jun 2004
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHROMIUM; DISSOLUTION; ELECTROLYTES; GLASS; HIGH-LEVEL RADIOACTIVE WASTES; HYDROXIDES; LEACHING; OXIDIZERS; REDOX REACTIONS; REMOVAL; SLUDGES; TANKS; WASHING; WASTE DISPOSAL; WASTES

Citation Formats

Rai, Dhanpat, Rao, Linfeng, and Clark, Sue B. SPECIATION, DISSOLUTION, AND REDOX REACTIONS OF CHROMIUM RELEVANT TO PRETREATMENT AND SEPARATION OF HIGH-LEVEL TANK WASTES. United States: N. p., 2004. Web. doi:10.2172/838639.
Rai, Dhanpat, Rao, Linfeng, & Clark, Sue B. SPECIATION, DISSOLUTION, AND REDOX REACTIONS OF CHROMIUM RELEVANT TO PRETREATMENT AND SEPARATION OF HIGH-LEVEL TANK WASTES. United States. https://doi.org/10.2172/838639
Rai, Dhanpat, Rao, Linfeng, and Clark, Sue B. Tue . "SPECIATION, DISSOLUTION, AND REDOX REACTIONS OF CHROMIUM RELEVANT TO PRETREATMENT AND SEPARATION OF HIGH-LEVEL TANK WASTES". United States. https://doi.org/10.2172/838639. https://www.osti.gov/servlets/purl/838639.
@article{osti_838639,
title = {SPECIATION, DISSOLUTION, AND REDOX REACTIONS OF CHROMIUM RELEVANT TO PRETREATMENT AND SEPARATION OF HIGH-LEVEL TANK WASTES},
author = {Rai, Dhanpat and Rao, Linfeng and Clark, Sue B},
abstractNote = {Chromium, one of the problematic elements in tank sludges, is considered the most important constituent in defining the total volume of high-level radioactive waste (HLW) glass. Current sludge washing processes (e.g. caustic leaching, 3 M NaOH) are not effective in removing Cr. This inefficient removal would result in production of an unacceptably large volume of HLW glass and thus a tremendous increase in the cost of waste disposal. This proposed research seeks to develop fundamental data for chromium (Cr) reactions that are not currently available but are essential for developing effective methodologies for removing Cr form high-level waste (HLW). Our objectives are to study (1) the dissolution of several solid phases (e.g., CrOOH, Cr2O3(c), Cr(OH)3, and Fe and Cr, binary hydroxides, identified to be important from sludge leaching studies) in highly alkaline solutions and in the presence of other electrolytes (e.g., carbonate, phosphate, sulfate, nitrite), and (2) the effect of the nature of Cr solid phases and aqueous species on their redox reactivity with a variety of potential oxidants (e.g., H2O2, persulfate, O2, and ferrate). This information will provide critical support for developing enhanced pretreatment strategies for removing Cr from HLW and will achieve a major cost reduction in HLW disposal.},
doi = {10.2172/838639},
url = {https://www.osti.gov/biblio/838639}, journal = {},
number = ,
volume = ,
place = {United States},
year = {2004},
month = {6}
}