skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes

Abstract

Ions intercalate or deintercalate into metal hexacyanoferrate to maintain charge neutrality when iron centers in the matrix are reduced or oxidized, respectively. Nickel hexacyanoferrate (NiHCF) is known to preferentially intercalate cesium over other alkali cations, thus providing a basis for separation. This program is studying potential-driven cation intercalation and deintercalation in metal hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties for cation mixtures, (2) enhancing ion exchange capacities, and (3) improving the material stability.

Authors:
Publication Date:
Research Org.:
University of Washington, Seattle, WA (US)
Sponsoring Org.:
USDOE Office of Environmental Management (EM) (US)
OSTI Identifier:
828572
Report Number(s):
EMSP-60123-2000
R&D Project: EMSP 60123; TRN: US0404027
DOE Contract Number:  
FG07-97ER14819
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 1 Jun 2000
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CATIONS; CESIUM; CLATHRATES; ELECTRODES; HYDROXIDES; ION EXCHANGE; IRON; MIXTURES; NICKEL; STABILITY

Citation Formats

Schwartz, Daniel T. Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes. United States: N. p., 2000. Web. doi:10.2172/828572.
Schwartz, Daniel T. Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes. United States. doi:10.2172/828572.
Schwartz, Daniel T. Thu . "Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes". United States. doi:10.2172/828572. https://www.osti.gov/servlets/purl/828572.
@article{osti_828572,
title = {Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes},
author = {Schwartz, Daniel T},
abstractNote = {Ions intercalate or deintercalate into metal hexacyanoferrate to maintain charge neutrality when iron centers in the matrix are reduced or oxidized, respectively. Nickel hexacyanoferrate (NiHCF) is known to preferentially intercalate cesium over other alkali cations, thus providing a basis for separation. This program is studying potential-driven cation intercalation and deintercalation in metal hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties for cation mixtures, (2) enhancing ion exchange capacities, and (3) improving the material stability.},
doi = {10.2172/828572},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {6}
}

Technical Report:

Save / Share: