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Title: Removal of chromium from groundwater using permeable barriers: An aquifer simulation study

Conference ·
OSTI ID:82818
 [1];  [2]
  1. Univ. of New Mexico, Albuquerque, NM (United States). Dept of Civil Engineering
  2. Army Environmental Policy Inst., Champaign, IL (United States)

Previous efforts to remediate groundwater contaminated by chromium-bearing industrial wastes have involved post-extraction methods, whereby groundwater is pumped to the surface treated and returned to the aquifer. This practice has proven effective for removing soluble pollutants. However, it is often costly and labor intensive and requires treating large volumes of water. Also, institutional obstacles such as ground and surface water discharge permits and groundwater rights must be considered. An alternative to conventional remediation methods is the in situ permeable barrier process, which intercepts soluble contaminants from solution but allows groundwater to flow through. Trench-based barriers, backfilled with reactive media, result in the direct adsorption of chemical species or the oxidation reduction of chemical species followed by precipitation. Laboratory studies were conducted to determine the technical feasibility of using trench-based media to remove chromium from groundwater. Removal of soluble hexavalent chromium (Cr(VI)) to concentrations less than the maximum contaminant level (MCL) for total chromium in drinking water (0.05 mg/l) was demonstrated with all candidate media in the aquifer simulation model. Adsorption appeared to be the principle mechanism of removal for all candidate media considered. Information gained from experience with the physical model was used in developing a computer generated, 1-D solute transport model to predict the movement of hexavalent chromium in an aquifer system.

OSTI ID:
82818
Report Number(s):
CONF-940789-; ISBN 0-7844-0031-8; TRN: IM9533%%276
Resource Relation:
Conference: American Society of Civil Engineers 1994 National Council on Environmental Engineering (NCEE) conference on critical issues in water and waste water treatment, Boulder, CO (United States), 11-13 Jul 1994; Other Information: PBD: 1994; Related Information: Is Part Of Critical issues in water and wastewater treatment. Proceedings of the 1994 national conference on environmental engineering; Ryan, J.N.; Edwards, M. [eds.] [Univ. of Colorado, Boulder, CO (United States). Dept of Civil, Environmental, and Architectural Engineering]; PB: 824 p.
Country of Publication:
United States
Language:
English