Simultaneous phosphorus and Si self-diffusion in extrinsic, isotopically controlled silicon heterostructures
We present experimental results of impurity and self-diffusion in an isotopically controlled silicon heterostructure extrinsically doped with phosphorus. As a consequence of extrinsic doping, the concentration of singly negatively charged native defects is enhanced and the role of these native defect charge states in the simultaneous phosphorus and Si self-diffusion can be determined. Multilayers of isotopically controlled {sup 28}Si and natural silicon enable simultaneous analysis of {sup 30}Si self-diffusion into the {sup 28}Si enriched layers and phosphorus diffusion throughout the multilayer structure. An amorphous 260 nm thick Si cap layer was deposited on top of the Si isotope heterostructure. The phosphorus ions were implanted to a depth such that all the radiation damage resided inside this amorphous cap layer, preventing the generation of excess native defects and enabling the determination of the Si self-diffusion coefficient and the phosphorus diffusivity under equilibrium conditions. These samples were annealed at temperatures between 950 and 1100 C to study the diffusion. Detailed analysis of the diffusion process was performed on the basis of a P diffusion model which involves neutral and positively charged mobile P species and neutral and singly negatively charged self-interstitial.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Director. Office of Science. Office of Basic Energy Sciences; UC Discovery Grant from the Industry-University Cooperative Research Program; U.S. National Science Foundation Grant DMR-0109844 (US)
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 826112
- Report Number(s):
- LBNL-55000; R&D Project: 513310; TRN: US200424%%448
- Resource Relation:
- Conference: 2004 MRS Spring Meeting, San Francisco, CA (US), 04/12/2004--04/16/2004; Other Information: PBD: 22 Apr 2003
- Country of Publication:
- United States
- Language:
- English
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