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Title: ansa-Calcocenes: trans-Ph2(CH3)2C2(eta5-C5H4)2Ca(DME)

Abstract

The molecular structure of the title compound is reported. [Part of final report for DOE contract FG02-98ER45709.]

Authors:
; ; ;
Publication Date:
Research Org.:
University of Idaho, Moscow, ID (US)
Sponsoring Org.:
USDOE Office of Energy Research (ER) (US)
OSTI Identifier:
808574
DOE Contract Number:
FG02-98ER45709
Resource Type:
Technical Report
Resource Relation:
Other Information: Acta Crystallographica, vol. E57 ISSN 1600-5368; PBD: 17 Aug 2001
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLECULAR STRUCTURE; CALCIUM COMPOUNDS; STRUCTURAL CHEMICAL ANALYSIS; ETHERS; ANSA-CALCOCENE; FULVENE COUPLING

Citation Formats

Twamley, Brendan, Matare, Gilbert, Shapiro, Pamela J., and Vij, Ashwani. ansa-Calcocenes: trans-Ph2(CH3)2C2(eta5-C5H4)2Ca(DME). United States: N. p., 2001. Web.
Twamley, Brendan, Matare, Gilbert, Shapiro, Pamela J., & Vij, Ashwani. ansa-Calcocenes: trans-Ph2(CH3)2C2(eta5-C5H4)2Ca(DME). United States.
Twamley, Brendan, Matare, Gilbert, Shapiro, Pamela J., and Vij, Ashwani. 2001. "ansa-Calcocenes: trans-Ph2(CH3)2C2(eta5-C5H4)2Ca(DME)". United States. doi:.
@article{osti_808574,
title = {ansa-Calcocenes: trans-Ph2(CH3)2C2(eta5-C5H4)2Ca(DME)},
author = {Twamley, Brendan and Matare, Gilbert and Shapiro, Pamela J. and Vij, Ashwani},
abstractNote = {The molecular structure of the title compound is reported. [Part of final report for DOE contract FG02-98ER45709.]},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = 2001,
month = 8
}

Technical Report:
Other availability
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  • This oral presentation described the intramolecular oxidation of an ansa-chromocene carbonyl complex through the electrophilic addition of a borane to the cyclopentadienyl ring followed by transfer of a proton from the ring to the metal center. A variety of zwitterionic, ring-borylated ansa-chromocene complexes were structurally and physically characterized. [Part of final report for DOE contract FG02-98ER45709.]
  • The molecular structure of the title compound is described. [Part of final report for DOE contract FG02-98ER45709.]
  • In this oral presentation, the synthesis and the physical and structural characterization of bimetallic and trimetallic complexes containing ansa-chromocene units bound to ferrocenyl isocyanide and 1,1'-diisocyanoferrocene units were described. [Part of final report for DOE contract FG02-98ER45709.]
  • This oral presentation reported that reacting ansa-chromocene carbonyl and t-butyl isocyanide complexes with B(C6F5)3 results in cyclopentadienyl ring borylation in the latter case and isocyanide ligand abstraction in the former. [Part of final report for DOE contract FG02-98ER45709.]
  • In this oral presentation, the synthesis and the physical and structural characterization of bimetallic and trimetallic complexes containing ansa-chromocene units bound to ferrocenyl isocyanide and 1,1'-diisocyanoferrocene units were described. [Part of final report for DOE contract FG02-98ER45709.]