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Title: O/M RATIO MEASUREMENT IN PURE AND MIXED OXIDE FULES - WHERE ARE WE NOW?

Abstract

The oxygen-to-metal (O/M) ratio is one of the most critical parameters of nuclear fuel fabrication, and its measurement is closely monitored for manufacturing process control and to ensure the service behavior of the final product. Thermogravimetry is the most widely used method, the procedure for which has remained largely unchanged since its development some thirty years ago. It was not clear to us, however, that this method is still the optimum one in light of advances in instrumentation, and in the current regulatory environment, particularly with regard to waste management and disposal. As part of the MOX fuel fabrication program at Los Alamos, we conducted a comprehensive review of methods for O/M measurements in UO{sub 2}, PuO{sub 2} and mixed oxide fuels for thermal reactors. A concerted effort was made to access information not available in the open literature. We identified approximately thirty five experimental methods that (a) have been developed with the intent of measuring O/M, (b) provided O/M indirectly by suitable reduction of the measured data, or (c) could provide O/M data with suitable data reduction or when combined with other methods. We will discuss the relative strengths and weaknesses of these methods in their application to currentmore » routine and small-lot production environment.« less

Authors:
;
Publication Date:
Research Org.:
Los Alamos National Lab., NM (US)
Sponsoring Org.:
US Department of Energy (US)
OSTI Identifier:
769099
Report Number(s):
LA-UR-00-5805
TRN: US0102605
DOE Contract Number:
W-7405-ENG-36
Resource Type:
Conference
Resource Relation:
Conference: Conference title not supplied, Conference location not supplied, Conference dates not supplied; Other Information: PBD: 1 Dec 2000
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; MIXED OXIDE FUELS; NUCLEAR FUELS; THERMAL GRAVIMETRIC ANALYSIS; MEASURING METHODS; COMPARATIVE EVALUATIONS; CONCENTRATION RATIO; OXYGEN; PLUTONIUM DIOXIDE; URANIUM DIOXIDE

Citation Formats

J. RUBIN, and ET AL. O/M RATIO MEASUREMENT IN PURE AND MIXED OXIDE FULES - WHERE ARE WE NOW?. United States: N. p., 2000. Web.
J. RUBIN, & ET AL. O/M RATIO MEASUREMENT IN PURE AND MIXED OXIDE FULES - WHERE ARE WE NOW?. United States.
J. RUBIN, and ET AL. Fri . "O/M RATIO MEASUREMENT IN PURE AND MIXED OXIDE FULES - WHERE ARE WE NOW?". United States. doi:. https://www.osti.gov/servlets/purl/769099.
@article{osti_769099,
title = {O/M RATIO MEASUREMENT IN PURE AND MIXED OXIDE FULES - WHERE ARE WE NOW?},
author = {J. RUBIN and ET AL},
abstractNote = {The oxygen-to-metal (O/M) ratio is one of the most critical parameters of nuclear fuel fabrication, and its measurement is closely monitored for manufacturing process control and to ensure the service behavior of the final product. Thermogravimetry is the most widely used method, the procedure for which has remained largely unchanged since its development some thirty years ago. It was not clear to us, however, that this method is still the optimum one in light of advances in instrumentation, and in the current regulatory environment, particularly with regard to waste management and disposal. As part of the MOX fuel fabrication program at Los Alamos, we conducted a comprehensive review of methods for O/M measurements in UO{sub 2}, PuO{sub 2} and mixed oxide fuels for thermal reactors. A concerted effort was made to access information not available in the open literature. We identified approximately thirty five experimental methods that (a) have been developed with the intent of measuring O/M, (b) provided O/M indirectly by suitable reduction of the measured data, or (c) could provide O/M data with suitable data reduction or when combined with other methods. We will discuss the relative strengths and weaknesses of these methods in their application to current routine and small-lot production environment.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Dec 01 00:00:00 EST 2000},
month = {Fri Dec 01 00:00:00 EST 2000}
}

Conference:
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