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Title: Inorganic, radioisotopic and organic analysis of 241-AP-101 tank waste

Abstract

Battelle received five samples from Hanford waste tank 241-AP-101, taken at five different depths within the tank. No visible solids or organic layer were observed in the individual samples. Individual sample densities were measured, then the five samples were mixed together to provide a single composite. The composite was homogenized and representative sub-samples taken for inorganic, radioisotopic, and organic analysis. All analyses were performed on triplicate sub-samples of the composite material. The sample composite did not contain visible solids or an organic layer. A subsample held at 10 C for seven days formed no visible solids. The characterization of the 241-AP-101 composite samples included: (1) Inductively-coupled plasma spectrometry for Ag, Al, Ba, Bi, Ca, Cd, Cr, Cu, Fe, K, La, Mg, Mn, Na, Nd, Ni, P, Pb, Pd, Ru, Rh, Si, Sr, Ti, U, Zn, and Zr (Note: Although not specified in the test plan, As, B, Be, Co, Li, Mo, Sb, Se, Sn, Tl, V, W, and Y were also measured and reported for information only) (2) Radioisotopic analyses for total alpha and total beta activities, {sup 3}H, {sup 14}C, {sup 60}Co, {sup 79}Se, {sup 90}Sr, {sup 99}Tc as pertechnetate, {sup 106}Ru/Rh, {sup 125}Sb, {sup 134}Cs, {sup 137}Cs, {supmore » 152}Eu, {sup 154}Eu, {sup 155}Eu, {sup 238}Pu, {sup 239+240}Pu, {sup 241}Am, {sup 242}Cm, and {sup 243+244}Cm; (3) Inductively-coupled plasma mass spectrometry for {sup 237}Np, {sup 239}Pu, {sup 240}Pu, {sup 99}Tc, {sup 126}Sn, {sup 129}I, {sup 231}Pa, {sup 233}U, {sup 234}U, {sup 235}U, {sup 236}U, {sup 238}U, {sup 241}AMU, {sup 242}AMU, {sup 243}AMU, As, B, Be, Ce, Co, Cs, Eu, I, Li, Mo, Pr, Rb, Sb, Se, Ta, Te, Th, Tl, V, and W; (4) total U by kinetic phosphorescence analysis; (5) Ion chromatography for Cl, F, NO{sub 2}, NO{sub 3}, PO{sub 4}, SO{sub 4}, acetate, formate, oxalate, and citrate; (6) Density, inorganic carbon and organic carbon by two different methods, mercury, free hydroxide, ammonia, and cyanide. The 241-AP-101 composite met all contract limits (molar ratio of analyte to sodium or ratio of becquerels of analyte to moles of sodium) defined in Specification 7 for Envelope A. Except for a few cases, the characterization results met or surpassed the quality control requirements established by the governing quality assurance plan and met or surpassed the minimum reportable quantity requirements specified by BNFL.« less

Authors:
; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
US Department of Energy (US)
OSTI Identifier:
757285
Report Number(s):
PNWD-3046; BNFL-RPT-046
R&D Project: 29953; Contract W375-LC-98-41698; TRN: US0003829
DOE Contract Number:  
AC06-76RL01830
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 28 Jun 2000
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; HANFORD RESERVATION; STORAGE FACILITIES; RADIOACTIVE WASTES; DENSITY; CHEMICAL COMPOSITION; MULTI-ELEMENT ANALYSIS; RADIOCHEMICAL ANALYSIS

Citation Formats

Fiskum, SK, Bredt, PR, Campbell, JA, Greenwood, LR, Farmer, OT, Lumetta, GJ, Mong, GM, Ratner, RT, Soderquist, CZ, Swoboda, RG, Urie, MW, and Wagner, JJ. Inorganic, radioisotopic and organic analysis of 241-AP-101 tank waste. United States: N. p., 2000. Web. doi:10.2172/757285.
Fiskum, SK, Bredt, PR, Campbell, JA, Greenwood, LR, Farmer, OT, Lumetta, GJ, Mong, GM, Ratner, RT, Soderquist, CZ, Swoboda, RG, Urie, MW, & Wagner, JJ. Inorganic, radioisotopic and organic analysis of 241-AP-101 tank waste. United States. https://doi.org/10.2172/757285
Fiskum, SK, Bredt, PR, Campbell, JA, Greenwood, LR, Farmer, OT, Lumetta, GJ, Mong, GM, Ratner, RT, Soderquist, CZ, Swoboda, RG, Urie, MW, and Wagner, JJ. 2000. "Inorganic, radioisotopic and organic analysis of 241-AP-101 tank waste". United States. https://doi.org/10.2172/757285. https://www.osti.gov/servlets/purl/757285.
@article{osti_757285,
title = {Inorganic, radioisotopic and organic analysis of 241-AP-101 tank waste},
author = {Fiskum, SK and Bredt, PR and Campbell, JA and Greenwood, LR and Farmer, OT and Lumetta, GJ and Mong, GM and Ratner, RT and Soderquist, CZ and Swoboda, RG and Urie, MW and Wagner, JJ},
abstractNote = {Battelle received five samples from Hanford waste tank 241-AP-101, taken at five different depths within the tank. No visible solids or organic layer were observed in the individual samples. Individual sample densities were measured, then the five samples were mixed together to provide a single composite. The composite was homogenized and representative sub-samples taken for inorganic, radioisotopic, and organic analysis. All analyses were performed on triplicate sub-samples of the composite material. The sample composite did not contain visible solids or an organic layer. A subsample held at 10 C for seven days formed no visible solids. The characterization of the 241-AP-101 composite samples included: (1) Inductively-coupled plasma spectrometry for Ag, Al, Ba, Bi, Ca, Cd, Cr, Cu, Fe, K, La, Mg, Mn, Na, Nd, Ni, P, Pb, Pd, Ru, Rh, Si, Sr, Ti, U, Zn, and Zr (Note: Although not specified in the test plan, As, B, Be, Co, Li, Mo, Sb, Se, Sn, Tl, V, W, and Y were also measured and reported for information only) (2) Radioisotopic analyses for total alpha and total beta activities, {sup 3}H, {sup 14}C, {sup 60}Co, {sup 79}Se, {sup 90}Sr, {sup 99}Tc as pertechnetate, {sup 106}Ru/Rh, {sup 125}Sb, {sup 134}Cs, {sup 137}Cs, {sup 152}Eu, {sup 154}Eu, {sup 155}Eu, {sup 238}Pu, {sup 239+240}Pu, {sup 241}Am, {sup 242}Cm, and {sup 243+244}Cm; (3) Inductively-coupled plasma mass spectrometry for {sup 237}Np, {sup 239}Pu, {sup 240}Pu, {sup 99}Tc, {sup 126}Sn, {sup 129}I, {sup 231}Pa, {sup 233}U, {sup 234}U, {sup 235}U, {sup 236}U, {sup 238}U, {sup 241}AMU, {sup 242}AMU, {sup 243}AMU, As, B, Be, Ce, Co, Cs, Eu, I, Li, Mo, Pr, Rb, Sb, Se, Ta, Te, Th, Tl, V, and W; (4) total U by kinetic phosphorescence analysis; (5) Ion chromatography for Cl, F, NO{sub 2}, NO{sub 3}, PO{sub 4}, SO{sub 4}, acetate, formate, oxalate, and citrate; (6) Density, inorganic carbon and organic carbon by two different methods, mercury, free hydroxide, ammonia, and cyanide. The 241-AP-101 composite met all contract limits (molar ratio of analyte to sodium or ratio of becquerels of analyte to moles of sodium) defined in Specification 7 for Envelope A. Except for a few cases, the characterization results met or surpassed the quality control requirements established by the governing quality assurance plan and met or surpassed the minimum reportable quantity requirements specified by BNFL.},
doi = {10.2172/757285},
url = {https://www.osti.gov/biblio/757285}, journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {6}
}