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Title: Synthesis, structure and properties of (CN{sub 3}H{sub 6}){sub 4}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated selenite

Abstract

An astonishing variety of inorganic networks templated by organic species have been reported over the last 10 years. A great deal of attention has been paid to the structure-directing role of the organic species, and the structural effect of variously coordinated cations, for example distorted octahedral vanadium and pyramidal tin. Less exploratory work has been carried out on the anionic part of the inorganic network, and most groups reported so far (phosphate, germanate, etc.) invariably adopt tetrahedral coordination. The possibilities of incorporating the pyramidal [HP0{sub 3}]{sup 2{minus}} hydrogen phosphite group into extended structures templated by inorganic, alkaline earth cations was explored a few years ago. In this paper the authors report the synthesis, crystal structure, and some properties of (CN{sub 3}H{sub 6}){sub 4}{center_dot}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated phase to contain the pyramidal selenite [SeO{sub 3}]{sup 2{minus}} anion.

Authors:
; ; ;
Publication Date:
Research Org.:
Sandia National Labs., Albuquerque, NM (US); Sandia National Labs., Livermore, CA (US)
Sponsoring Org.:
US Department of Energy (US)
OSTI Identifier:
756122
Report Number(s):
SAND2000-1275J
TRN: AH200021%%138
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Journal Article
Journal Name:
Angew. Chem. Int. Eng.
Additional Journal Information:
Other Information: Submitted to Angew. Chem. Int. Eng.; PBD: 22 May 2000
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ZINC COMPOUNDS; SELENITES; CYANIDES; SYNTHESIS; CRYSTAL STRUCTURE

Citation Formats

HARRISON,W.T.A., PHILLIPS,MARK L.F., STANCHFIELD,JESSE L., and NENOFF,TINA M. Synthesis, structure and properties of (CN{sub 3}H{sub 6}){sub 4}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated selenite. United States: N. p., 2000. Web. doi:10.1002/1521-3757(20001103)112:21<3966::AID-ANGE3966>3.3.CO;2-D.
HARRISON,W.T.A., PHILLIPS,MARK L.F., STANCHFIELD,JESSE L., & NENOFF,TINA M. Synthesis, structure and properties of (CN{sub 3}H{sub 6}){sub 4}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated selenite. United States. doi:10.1002/1521-3757(20001103)112:21<3966::AID-ANGE3966>3.3.CO;2-D.
HARRISON,W.T.A., PHILLIPS,MARK L.F., STANCHFIELD,JESSE L., and NENOFF,TINA M. Mon . "Synthesis, structure and properties of (CN{sub 3}H{sub 6}){sub 4}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated selenite". United States. doi:10.1002/1521-3757(20001103)112:21<3966::AID-ANGE3966>3.3.CO;2-D. https://www.osti.gov/servlets/purl/756122.
@article{osti_756122,
title = {Synthesis, structure and properties of (CN{sub 3}H{sub 6}){sub 4}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated selenite},
author = {HARRISON,W.T.A. and PHILLIPS,MARK L.F. and STANCHFIELD,JESSE L. and NENOFF,TINA M.},
abstractNote = {An astonishing variety of inorganic networks templated by organic species have been reported over the last 10 years. A great deal of attention has been paid to the structure-directing role of the organic species, and the structural effect of variously coordinated cations, for example distorted octahedral vanadium and pyramidal tin. Less exploratory work has been carried out on the anionic part of the inorganic network, and most groups reported so far (phosphate, germanate, etc.) invariably adopt tetrahedral coordination. The possibilities of incorporating the pyramidal [HP0{sub 3}]{sup 2{minus}} hydrogen phosphite group into extended structures templated by inorganic, alkaline earth cations was explored a few years ago. In this paper the authors report the synthesis, crystal structure, and some properties of (CN{sub 3}H{sub 6}){sub 4}{center_dot}Zn{sub 3}(SeO{sub 3}){sub 5}, the first organically-templated phase to contain the pyramidal selenite [SeO{sub 3}]{sup 2{minus}} anion.},
doi = {10.1002/1521-3757(20001103)112:21<3966::AID-ANGE3966>3.3.CO;2-D},
journal = {Angew. Chem. Int. Eng.},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {5}
}