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Title: Radiation polymerizable coating composition containing an unsaturated phosphoric ester. [ionizing radiations]

Abstract

A radiation polymerizable protective coating composition or paint consists essentially of a binder solution of: (1) between about 90 and about 10 parts of a saturated, thermoplastic vinyl polymer prepared from at least about 85 weight percent of monofunctional vinyl monomers; (2) between about 10 and about 90 parts of vinyl solvent monomers for the vinyl polymer, at least about 10 weight percent, preferably at least about 30 weight percent, of the solvent monomers being selected from the group consisting of divinyl monomers, trivinyl monomers, tetravinyl monomers and mixtures of these; and (3) between about 1.0 and about 15.0 parts per 100 parts of the total of the thermoplastic vinyl polymer and the vinyl solvent monomers of a triester of phosphoric acid bearing one or more sites of vinyl unsaturation. The composition exhibits excellent quality and good adhesion to a variety of substrates, in particular metals, including vapor deposited metals. Preferred articles bearing such a coating are prepared by applying a base coat to a substrate and curing the same; vapor depositing a coating of metal over the surface of the base coat; and applying to and curing on the surface of the deposited metal the radiation polymerizable topcoat, preferablymore » with little or no pigment contained therein. 7 claims, no drawings.« less

Inventors:
;
Publication Date:
OSTI Identifier:
7267340
Patent Number(s):
US 3957918
Application Number:
TRN: 08-019529
Assignee:
Ford Motor Co.
Resource Type:
Patent
Resource Relation:
Patent File Date: Filed date 31 Dec 1974
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; POLYVINYLS; CHEMICAL RADIATION EFFECTS; VINYL MONOMERS; CROSS-LINKING; IONIZING RADIATIONS; POLYMERIZATION; PROTECTIVE COATINGS; CHEMICAL REACTIONS; CHEMISTRY; COATINGS; MONOMERS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYMERS; RADIATION CHEMISTRY; RADIATION EFFECTS; RADIATIONS; 400600* - Radiation Chemistry

Citation Formats

Dickie, R A, and Cassatta, J C. Radiation polymerizable coating composition containing an unsaturated phosphoric ester. [ionizing radiations]. United States: N. p., 1976. Web.
Dickie, R A, & Cassatta, J C. Radiation polymerizable coating composition containing an unsaturated phosphoric ester. [ionizing radiations]. United States.
Dickie, R A, and Cassatta, J C. Tue . "Radiation polymerizable coating composition containing an unsaturated phosphoric ester. [ionizing radiations]". United States.
@article{osti_7267340,
title = {Radiation polymerizable coating composition containing an unsaturated phosphoric ester. [ionizing radiations]},
author = {Dickie, R A and Cassatta, J C},
abstractNote = {A radiation polymerizable protective coating composition or paint consists essentially of a binder solution of: (1) between about 90 and about 10 parts of a saturated, thermoplastic vinyl polymer prepared from at least about 85 weight percent of monofunctional vinyl monomers; (2) between about 10 and about 90 parts of vinyl solvent monomers for the vinyl polymer, at least about 10 weight percent, preferably at least about 30 weight percent, of the solvent monomers being selected from the group consisting of divinyl monomers, trivinyl monomers, tetravinyl monomers and mixtures of these; and (3) between about 1.0 and about 15.0 parts per 100 parts of the total of the thermoplastic vinyl polymer and the vinyl solvent monomers of a triester of phosphoric acid bearing one or more sites of vinyl unsaturation. The composition exhibits excellent quality and good adhesion to a variety of substrates, in particular metals, including vapor deposited metals. Preferred articles bearing such a coating are prepared by applying a base coat to a substrate and curing the same; vapor depositing a coating of metal over the surface of the base coat; and applying to and curing on the surface of the deposited metal the radiation polymerizable topcoat, preferably with little or no pigment contained therein. 7 claims, no drawings.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1976},
month = {5}
}