Hybridization interaction between helium and a metal surface
Journal Article
·
· Phys. Rev. B: Condens. Matter; (United States)
In order to calculate potentials for helium-atom diffraction from surfaces it is important to include the hybridization between the helium 1s orbital and the unoccupied states in the metal, since this term is strongly anticorrugating. In this paper we calculate the magnitude of the hybridization energy for helium near a jellium surface. This calculation shows that the hybridization is a large effect, and is sufficient to explain the anomalously small corrugations observed on clean metal surfaces. The calculation of the hybridization energy takes into account the effects of the surface image potential, which provides a large perturbation of the helium 1s orbital.
- Research Organization:
- Cavendish Laboratory, University of Cambridge, Madingley Road, Cambridge CB3XE, United Kingdom
- OSTI ID:
- 7262124
- Journal Information:
- Phys. Rev. B: Condens. Matter; (United States), Vol. 34:10
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
HELIUM
COLLISIONS
METALS
ATOM COLLISIONS
CHARGE DENSITY
ELECTRONIC STRUCTURE
HYBRIDIZATION
INVERSE SCATTERING PROBLEM
MILLI EV RANGE
POTENTIAL SCATTERING
SURFACES
ELASTIC SCATTERING
ELEMENTS
ENERGY RANGE
EV RANGE
FLUIDS
GASES
NONMETALS
RARE GASES
SCATTERING
640301* - Atomic
Molecular & Chemical Physics- Beams & their Reactions
GENERAL PHYSICS
HELIUM
COLLISIONS
METALS
ATOM COLLISIONS
CHARGE DENSITY
ELECTRONIC STRUCTURE
HYBRIDIZATION
INVERSE SCATTERING PROBLEM
MILLI EV RANGE
POTENTIAL SCATTERING
SURFACES
ELASTIC SCATTERING
ELEMENTS
ENERGY RANGE
EV RANGE
FLUIDS
GASES
NONMETALS
RARE GASES
SCATTERING
640301* - Atomic
Molecular & Chemical Physics- Beams & their Reactions