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Title: Use of Hysol US0009 polyurethane encapsulant in battery cables

Abstract

This report describes the evaluation of Hysol US0009 polyurethane as an encapsulant for the battery cable used on the MC1605B. The Hysol resin was selected for the application because it was reacted with a non-carcinogenic curing agent and because it exhibited superior mechanical, electrical, and hydrolytic properties over a wide temperature range. The Hysol encapsulant was evaluated to determine if it was superior to the EN-7 elastomer as a sealant against electrolyte migration to the interior of the cable. Environmental tests reported here showed the Hysol was marginal when no preseal was employed but was 100 percent effective when a bird-cage seal was used inside the EMR hardware. The EN-7 encapsulant, on the other hand, was effective only when seals were employed both inside the EMR hardware and at the lug terminations. Without the two preseals, the EN-7 compound was always unsatisfactory. Twenty development battery cables fabricated with Hysol under production operations were tested after alternate immersion in battery electrolyte and after exposures to temperature shock and the MIL-STD 202 environment. Presealed cables successfully survived these exposures and retained their initial DC resistance, insulation resistance, and high potential properties with only minor changes. The environmental tests conducted with these assembliesmore » probably represented five or more years of in-field service. Comparative peel tests demonstrated that the Hysol/neoprene insert bond was twice (5.2 versus 2.8 kg/cm) that of the EN-7 polyurethane. Hysol US0009 has a potential for encapsulation of other WR components and assemblies in which the EN-7 resin has exhibited thermal shortcomings. 7 figures, 10 tables.« less

Authors:
Publication Date:
Research Org.:
Sandia Labs., Albuquerque, NM (USA)
OSTI Identifier:
7253409
Report Number(s):
SAND-77-0411
DOE Contract Number:
EY-76-C-04-0789
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; ELECTRIC BATTERIES; ELECTRIC CABLES; FABRICATION; ELECTROLYTES; PERFORMANCE TESTING; POLYURETHANES; POTASSIUM HYDROXIDES; ALKALI METAL COMPOUNDS; CABLES; CONDUCTOR DEVICES; ELECTRICAL EQUIPMENT; ELECTROCHEMICAL CELLS; ENERGY STORAGE SYSTEMS; EQUIPMENT; HYDROGEN COMPOUNDS; HYDROXIDES; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; PETROCHEMICALS; PETROLEUM PRODUCTS; PLASTICS; POLYAMIDES; POLYMERS; POTASSIUM COMPOUNDS; TESTING; 250903* - Energy Storage- Batteries- Materials, Components, & Auxiliaries

Citation Formats

Voida, G. Use of Hysol US0009 polyurethane encapsulant in battery cables. United States: N. p., 1977. Web. doi:10.2172/7253409.
Voida, G. Use of Hysol US0009 polyurethane encapsulant in battery cables. United States. doi:10.2172/7253409.
Voida, G. Fri . "Use of Hysol US0009 polyurethane encapsulant in battery cables". United States. doi:10.2172/7253409. https://www.osti.gov/servlets/purl/7253409.
@article{osti_7253409,
title = {Use of Hysol US0009 polyurethane encapsulant in battery cables},
author = {Voida, G.},
abstractNote = {This report describes the evaluation of Hysol US0009 polyurethane as an encapsulant for the battery cable used on the MC1605B. The Hysol resin was selected for the application because it was reacted with a non-carcinogenic curing agent and because it exhibited superior mechanical, electrical, and hydrolytic properties over a wide temperature range. The Hysol encapsulant was evaluated to determine if it was superior to the EN-7 elastomer as a sealant against electrolyte migration to the interior of the cable. Environmental tests reported here showed the Hysol was marginal when no preseal was employed but was 100 percent effective when a bird-cage seal was used inside the EMR hardware. The EN-7 encapsulant, on the other hand, was effective only when seals were employed both inside the EMR hardware and at the lug terminations. Without the two preseals, the EN-7 compound was always unsatisfactory. Twenty development battery cables fabricated with Hysol under production operations were tested after alternate immersion in battery electrolyte and after exposures to temperature shock and the MIL-STD 202 environment. Presealed cables successfully survived these exposures and retained their initial DC resistance, insulation resistance, and high potential properties with only minor changes. The environmental tests conducted with these assemblies probably represented five or more years of in-field service. Comparative peel tests demonstrated that the Hysol/neoprene insert bond was twice (5.2 versus 2.8 kg/cm) that of the EN-7 polyurethane. Hysol US0009 has a potential for encapsulation of other WR components and assemblies in which the EN-7 resin has exhibited thermal shortcomings. 7 figures, 10 tables.},
doi = {10.2172/7253409},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Apr 01 00:00:00 EST 1977},
month = {Fri Apr 01 00:00:00 EST 1977}
}

Technical Report:

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  • Presented is a procedure for determining the iron content in a polyurethane encapsulant curing agent by x-ray emission spectroscopy. Standards were prepared by adding ferric acetyl acetonate to a curing agent of identical composition to that being analyzed, but containing no iron. Results show that x-ray emission spectroscopy is feasible for determination of iron in the 30 to 50 ppM range. This range could probably be extended by the preparation of additional standards. Precision of the method is approximately 1.2 ppM at the 99 percent confidence level.
  • The preparation of polyurethane encapsulants, based on polyether diol/diisocyanate prepolymers and 1,4-butanediol, which are soluble in several organic solvents, was investigated. Since these materials can be easily removed, repair of electronic circuitry found defective in potted units can be readily accomplished. Polyether diols of varying molecular weights were reacted with toluene diisocyanate (TDI) and methylene diphenylisocyanate (MDI) to produce stable prepolymers. Several properties of both the isocyanate prepolymers and 1,4-butanediol cured polyurethane encapsulants are presented.
  • The inventigation of materials which could be used for fabricating elastomeric seals for geothermal well logging equipment is described. The seals were to be made either from a methylphenylcarborane-siloxane base gum stock, or from new fluoroelastomer compounds synthesized at Hughes Aircraft Company. A literature search was made to obtain data on carborane-siloxane polymers, synthesis routes for fluorinated elastomers and high temperature hydrolytic stability tests of elastomers. Information was obtained on the first two topics, but very little was available on hydrolysis testing. A number of compounds, based on carborane-siloxane, were formulated and cured. Compression set, hardness and shrinkage tests withmore » postcure variations were made on the most promising formulations. A simple hydrolytic stability test at 275/sup 0/C (525/sup 0/F) and 830 psi was developed which indicated that both the carborane and siloxane bonds were easily broken after short exposure periods. Thermodynamic calculatons indicated that this result could be expected. Because of the agreement between empirical and theoretical data, work on the carborane-siloxanes was discontinued after approximately the first year. Synthesis efforts to produce a highly fluorinated elastomer based on perfluorolkylene oxide were continued through the entrie program. None of these routes produced a satisfactory elastomer.« less