Structure of oriented V sub 2 O sub 5 gel studied by polarized x-ray-absorption spectroscopy at the vanadium K edge
- Dipartimento di Matematica e Fisica, Universita di Camerino, I-62032 Camerino, (Italy)
- Instituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, I-00044 Frascati, (Italy)
- Instituto de Ciencia de Materiales de Aragon, Consejo Superior de Investigaciones Cientificas, Universidad de Zaragoza, 50009 Zaragoza, (Spain)
- Dipartimento di Fisica, Universita di Roma, La Sapienza,'' I-00185 Roma, (Italy)
The local structure around the vanadium site in the oriented V{sub 2}O{sub 5}{center dot}1.6 H{sub 2}O dehydrated xerogel phase is investigated by polarized x-ray-absorption spectroscopy (XAS). A large dychroism is found both in the extended x-ray-absorption fine structure (EXAFS) and in x-ray-absorption near-edge structure (XANES). A joint analysis of EXAFS and XANES data is reported. EXAFS analysis has been performed using a spherical-wave propagator and XANES analysis by full multiple-scattering calculation. A detailed discussion about the origin of all the different features in the experimental XAS spectra and a method to extract small contributions in the EXAFS part of the spectrum is presented. Moreover, the local structure around the vanadium atom in the V{sub 2}O{sub 5} hydrogel phase is derived.
- OSTI ID:
- 7246930
- Journal Information:
- Physical Review, B: Condensed Matter; (USA), Vol. 40:18; ISSN 0163-1829
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
VANADIUM OXIDES
CHEMICAL BONDS
ABSORPTION SPECTROSCOPY
DICHROISM
GELS
HYDRATES
MULTIPLE SCATTERING
ORIENTATION
POLARIZATION
PROPAGATOR
X RADIATION
CHALCOGENIDES
COLLOIDS
DISPERSIONS
ELECTROMAGNETIC RADIATION
IONIZING RADIATIONS
OXIDES
OXYGEN COMPOUNDS
RADIATIONS
SCATTERING
SPECTROSCOPY
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
360202* - Ceramics
Cermets
& Refractories- Structure & Phase Studies