Magic numbers in kinetic energy releases for unimolecular decompositions of (NH sub 3 ) sub n H sup + ion clusters
Abstract
The average kinetic energy (T) released during unimolecular decomposition of protonated ammonia ion clusters, (NH{sub 3}){sub n}H{sup +}, has been measured as a function of cluster size for n = 2-8. There is a pronounced discontinuity in the generally rising function of (T) with n, reflecting the filling of the first solvation shell at n = 5.
- Authors:
-
- Hebrew Univ. of Jerusalem (Israel)
- Publication Date:
- OSTI Identifier:
- 7171183
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Physical Chemistry; (USA)
- Additional Journal Information:
- Journal Volume: 93:15; Journal ID: ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 10 SYNTHETIC FUELS; AMMONIA; DECOMPOSITION; DATA ANALYSIS; EXPERIMENTAL DATA; IONS; KINETIC ENERGY; MEASURING INSTRUMENTS; MEASURING METHODS; CHARGED PARTICLES; CHEMICAL REACTIONS; DATA; ENERGY; HYDRIDES; HYDROGEN COMPOUNDS; INFORMATION; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NUMERICAL DATA; 400000* - Chemistry; 400200 - Inorganic, Organic, & Physical Chemistry; 100300 - Synthetic Fuels- Properties & Composition- (1990-)
Citation Formats
Lifshitz, C, and Louage, F. Magic numbers in kinetic energy releases for unimolecular decompositions of (NH sub 3 ) sub n H sup + ion clusters. United States: N. p., 1989.
Web. doi:10.1021/j100352a001.
Lifshitz, C, & Louage, F. Magic numbers in kinetic energy releases for unimolecular decompositions of (NH sub 3 ) sub n H sup + ion clusters. United States. https://doi.org/10.1021/j100352a001
Lifshitz, C, and Louage, F. Thu .
"Magic numbers in kinetic energy releases for unimolecular decompositions of (NH sub 3 ) sub n H sup + ion clusters". United States. https://doi.org/10.1021/j100352a001.
@article{osti_7171183,
title = {Magic numbers in kinetic energy releases for unimolecular decompositions of (NH sub 3 ) sub n H sup + ion clusters},
author = {Lifshitz, C and Louage, F},
abstractNote = {The average kinetic energy (T) released during unimolecular decomposition of protonated ammonia ion clusters, (NH{sub 3}){sub n}H{sup +}, has been measured as a function of cluster size for n = 2-8. There is a pronounced discontinuity in the generally rising function of (T) with n, reflecting the filling of the first solvation shell at n = 5.},
doi = {10.1021/j100352a001},
url = {https://www.osti.gov/biblio/7171183},
journal = {Journal of Physical Chemistry; (USA)},
issn = {0022-3654},
number = ,
volume = 93:15,
place = {United States},
year = {1989},
month = {7}
}
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