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Title: Isotopically heavy oxygen-containing siderite derived from the decomposition of methane hydrate

Journal Article · · Geology; (USA)

Authigenic siderite from the Miocene and Pliocene sediments of the Blake Outer Ridge formed in a methane fermentation zone in equilibrium with anomalously heavy oxygen water, as evidenced by its heavy-carbon ({minus}1.6 to +12.5 {delta}{sup 13}C) and heavy-oxygen (+0.1 to +7.9 {delta}{sup 18}O) values. Blake Outer Ridge sediments are impregnated with methane hydrate, which is generally enriched in {sup 18}O relative to ambient water. This suggests that decomposition of methane hydrate and subsequent release of large amounts of methane and heavy oxygen water affected the formation of the {sup 18}O-enriched siderite. Gas hydrate reaction in sediments is an important process for causing a dramatic variation of oxygen isotopic composition of the interstitial water and of authigenic carbonates formed during burial diagenesis.

OSTI ID:
7154757
Journal Information:
Geology; (USA), Vol. 17:8; ISSN 0091-7613
Country of Publication:
United States
Language:
English

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