Does Marcus-Hush theory really work Optical studies of intervalence transfer in acetylene-bridged biferrocene monocation at infinite dilution and at finite ionic strengths

Journal Article · Thu Mar 08 00:00:00 EST 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100368a016· OSTI ID:7140647

Blackbourn, R L; Hupp, J T ^[1]

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1. Northwestern Univ., Evanston, IL (USA)

Intervalence charge-transfer data for acetylene-bridged biferrocene monocation (Bf{sup +}) have been collected in five solvents in the presence and absence of excess electrolyte and in the limit of infinite chromophore dilution. The study was motivated by earlier work which demonstrated that the intervalence absorption maximum for Bf{sup +} in methylene chloride could vary substantially with both chromophore concentration and added electrolyte concentration. In the present study similar (but smaller) variations are found in other solvents.

• OSTI ID: 7140647
• Journal Information: Journal of Physical Chemistry; (USA), Vol. 94:5; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
FERROCENE
CHARGE TRANSPORT
ACETYLENE
CATIONS
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
OPTICAL PROPERTIES
ALKYNES
CHARGED PARTICLES
COMPLEXES
DATA
DIENES
HYDROCARBONS
INFORMATION
IONS
IRON COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POLYENES
TRANSITION ELEMENT COMPLEXES
400500* - Photochemistry