Nonspectator electron processes in resonant Auger spectra of SiCl/sub 4/

Journal Article · Sat Oct 15 00:00:00 EDT 1988 · J. Chem. Phys.; (United States)

OSTI ID:7087710

Carlson, T A; Mullins, D R; Beall, C E; Yates, B W; Taylor, J W; Grimm, F A

Angle-resolved photoelectron spectroscopy has been carried out on the valence shell of SiCl/sub 4/ over the range of photon energies from 101.5 to 112.5 eV. Both intensities and angular distribution parameters ..beta.. were monitored over the preionization resonances for silicon 2p. Little effect was seen for emission from the chlorine lone-pair orbitals 2t/sub 1/ , 8t/sub 2/ , and 2e, but striking effects were seen for the bonding 7t/sub 2/ orbital. The resonant behavior was compared with photoabsorption data. The results are discussed in terms of direct participation of the resonantly excited electron and this process compared with spectator electron and shakeup processes.

• Research Organization: Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6201
• OSTI ID: 7087710
• Journal Information: J. Chem. Phys.; (United States), Vol. 89:8
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
SILICON CHLORIDES
AUGER ELECTRON SPECTROSCOPY
INNER-SHELL IONIZATION
PHOTOIONIZATION
ANGULAR DISTRIBUTION
EV RANGE 10-100
PHOTOELECTRON SPECTROSCOPY
SYNCHROTRON RADIATION
BREMSSTRAHLUNG
CHLORIDES
CHLORINE COMPOUNDS
DISTRIBUTION
ELECTROMAGNETIC RADIATION
ELECTRON SPECTROSCOPY
ENERGY RANGE
EV RANGE
HALIDES
HALOGEN COMPOUNDS
IONIZATION
RADIATIONS
SILICON COMPOUNDS
SPECTROSCOPY
400201* - Chemical & Physicochemical Properties