Structural studies of precursor and partially oxidized conducting salts. 12. Crystal structure of Rb/sub 2/(Pt(CN)/sub 4/)(FHF)/sub 040/. A new lower limit for the platinum--platinum separation and the first anhydrous one-dimensional tetracyanoplatinate complex
Journal Article
·
· Inorg. Chem.; (United States)
OSTI ID:7078220
The synthesis and crystal structure of a new partially oxidized tetracyanoplatinate complex containing the triatomic bifluoride ion (FHF)/sup -/ is reported. This complex has the shortest Pt--Pt distance yet observed for any POTCP complex. X-ray data and thermal gravimetric analysis of the Rb salt and its Cs analog showed no evidence for the presence of water; therefore the complexes are believed to be the first anhydrous POTCP complexes. (JSR)
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 7078220
- Journal Information:
- Inorg. Chem.; (United States), Vol. 16:8
- Country of Publication:
- United States
- Language:
- English
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Structural studies of precursor and partially oxidized conducting complexes. IX. The new one-dimensional tetracyanoplatinates, M/sub 2/(Pt(CN)/sub 4/)(FHF)/sub 0/ /sub 39/. xH/sub 2/O (M = Rb, Cs), and a new lower limit for the platinum--platinum separation (2. 80 A)
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Wed Mar 02 00:00:00 EST 1977
· J. Am. Chem. Soc.; (United States)
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OSTI ID:7078220