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Title: Impact of indoor environmental parameters on formaldehyde concentrations in unoccupied research houses

Journal Article · · J. Air Pollut. Control Assoc.; (United States)

An environmental parameters study has examined the impact of indoor temperature (T) and relative humidity (RH) levels on formaldehyde (CH/sub 2/O) concentrations inside two unoccupied research houses where the primary CH/sub 2/O emitter is particleboard underlayment. The data were fit to a simple three-term, steady state model describing the T and RH dependence of CH/sub 2/O concentration in a single compartment with a single CH/sub 2/O emitter. The model incorporates an Arrhenius T dependence and a nonlinear RH dependence of the CH/sub 2/O vapor concentration within the solid CH/sub 2/O emitter. The RH dependence is based on Freundlich's theory of the adsorption of water vapor on solid surfaces. The model is used to estimate potential seasonal variation in CH/sub 2/O concentrations under specified experimental conditions inside the research houses. The modeled results indicate six- to ninefold variation between 18/sup 0/C, 20% RH and 32/sup 0/C, 80% RH, simulating potential winter/summer conditions with minimal indoor climate control. In comparison, indoor conditions ranging from 20/sup 0/C, 30% RH to 26/sup 0/C, 60% RH yielded approximate two- to fourfold fluctuations in CH/sub 2/O concentration. The research house data were also used to evaluate the limitations and applicability of more complex five-term models developed from small-scale chamber studies of the environmental dependence of CH/sub 2/O emissions from particleboard underlayment.

Research Organization:
Oak Ridge National Lab., TN
OSTI ID:
7037452
Journal Information:
J. Air Pollut. Control Assoc.; (United States), Vol. 36:11
Country of Publication:
United States
Language:
English