Protocol for determination of chemical warfare agent simulant movement through porous media
In the event of an unplanned release of chemical warfare agent during any phase of the Chemical Stockpile Disposal Program (CSDP), a (small) potential exists for contamination of buildings and materials used in their construction. Guidelines for unrestricted access to potentially agent-contaminated private and public property are presently undefined due to uncertainties regarding the adequacy of decontaminating porous surfaces such as wood, masonry and gypsum wall board. Persistent agents such as VX or mustard are particularly problematic. The report which follows documents a measurement protocol developed in a scoping investigation characterizing the permeation of chemical warfare agent simulants (diisopropylmethyl phosphonate (DIMP) for warfare agent GB, dimethylmethyl phosphonate (DMMP) for warfare agent VX and chlorethylethyl sulfide (CEES) for warfare agent sulfur mustard) through several, common porous, construction materials. The porous media'' selected for examination were wood, brick, cinder block, and gypsum wall board. Simulants were tested rather than actual warfare agents because of their low toxicity, commercial availability, and the lack of surety capability at Oak Ridge National Laboratory (ORNL). The present work is considered a protocol for confirmation testing with live'' agents.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOD; Department of Defense, Washington, DC (United States)
- DOE Contract Number:
- AC05-84OR21400
- OSTI ID:
- 7037331
- Report Number(s):
- ORNL/TM-12002; ON: DE92019932
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
BUILDING MATERIALS
CONTAMINATION
PERMEABILITY
CHEMICAL WARFARE AGENTS
DIFFUSION
CHROMATOGRAPHY
DECONTAMINATION
POROUS MATERIALS
SIMULATION
CLEANING
MATERIALS
SEPARATION PROCESSES
WEAPONS
450600* - Military Technology
Weaponry
& National Defense- Chemical & Biological- (1990)