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Title: Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide

Abstract

Coordinatively saturated cationic ruthenium(II) complexes, (eta/sup 5/-C/sub 5/H/sub 5/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (1), (eta/sup 5/-C/sub 5/Me/sub 5/)(eta/sup 6/-C/sub 66/)Ru/sup II/)(BF/sub 4/) (2), ((1-5-eta/sup 5/-C/sub 6/H/sub 7/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (3), ((1-5-eta/sup 5/-C/sub 7/H/sub 9/)(eta/sup 6/-C/sub 6/H/sub 7/)Ru/sup II/)(BF/sub 4/) (4), ((1-3:5,6-eta/sup 5/-C/sub 8/H/sub 1/exclamation)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BG/sub 4/)(5), and ((6-EtO-1-5-eta /sup 5/-C/sub 7/H/sub 8/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (7), are prepared by the reaction of (eta/sup 6/-C/sub 6/H/sub 6/)RuCl/sub 2/)/sub 2/ with cyclopentadiene, pentamethylcyclopentadiene, 1,3-cyclohexadiene, 1,3-cycloheptadiene, 1,5-cyclooctadiene, and 1,3,5-cycloheptatriene, respectively, in ethanol in the presence of AgBF/sub 4/. Superoxide anion attacks at the terminal position of the dienyl moiety of 3-5 to yield ruthenium(0) complexes 8-10, containing cyclic dienone ligand. 25 references, 4 figures, 4 tables.

Authors:
; ;
Publication Date:
Research Org.:
Tokyo Institute of Technology (Japan)
OSTI Identifier:
7032640
Resource Type:
Journal Article
Journal Name:
Inorg. Chem.; (United States)
Additional Journal Information:
Journal Volume: 25:19
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALKENES; OXIDATION; AROMATICS; CHEMICAL PREPARATION; CHEMICAL REACTIONS; BORON FLUORIDES; ORGANOMETALLIC COMPOUNDS; POTASSIUM COMPOUNDS; RUTHENIUM COMPLEXES; SUPEROXIDE RADICALS; ETHANOL; EXPERIMENTAL DATA; ALCOHOLS; ALKALI METAL COMPOUNDS; BORON COMPOUNDS; COMPLEXES; DATA; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; HYDROXY COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; RADICALS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties

Citation Formats

Oshima, N, Suzuki, H, and Moro-oka, Y. Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide. United States: N. p., 1986. Web. doi:10.1021/ic00239a018.
Oshima, N, Suzuki, H, & Moro-oka, Y. Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide. United States. https://doi.org/10.1021/ic00239a018
Oshima, N, Suzuki, H, and Moro-oka, Y. 1986. "Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide". United States. https://doi.org/10.1021/ic00239a018.
@article{osti_7032640,
title = {Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide},
author = {Oshima, N and Suzuki, H and Moro-oka, Y},
abstractNote = {Coordinatively saturated cationic ruthenium(II) complexes, (eta/sup 5/-C/sub 5/H/sub 5/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (1), (eta/sup 5/-C/sub 5/Me/sub 5/)(eta/sup 6/-C/sub 66/)Ru/sup II/)(BF/sub 4/) (2), ((1-5-eta/sup 5/-C/sub 6/H/sub 7/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (3), ((1-5-eta/sup 5/-C/sub 7/H/sub 9/)(eta/sup 6/-C/sub 6/H/sub 7/)Ru/sup II/)(BF/sub 4/) (4), ((1-3:5,6-eta/sup 5/-C/sub 8/H/sub 1/exclamation)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BG/sub 4/)(5), and ((6-EtO-1-5-eta /sup 5/-C/sub 7/H/sub 8/)(eta/sup 6/-C/sub 6/H/sub 6/)Ru/sup II/)(BF/sub 4/) (7), are prepared by the reaction of (eta/sup 6/-C/sub 6/H/sub 6/)RuCl/sub 2/)/sub 2/ with cyclopentadiene, pentamethylcyclopentadiene, 1,3-cyclohexadiene, 1,3-cycloheptadiene, 1,5-cyclooctadiene, and 1,3,5-cycloheptatriene, respectively, in ethanol in the presence of AgBF/sub 4/. Superoxide anion attacks at the terminal position of the dienyl moiety of 3-5 to yield ruthenium(0) complexes 8-10, containing cyclic dienone ligand. 25 references, 4 figures, 4 tables.},
doi = {10.1021/ic00239a018},
url = {https://www.osti.gov/biblio/7032640}, journal = {Inorg. Chem.; (United States)},
number = ,
volume = 25:19,
place = {United States},
year = {Wed Sep 10 00:00:00 EDT 1986},
month = {Wed Sep 10 00:00:00 EDT 1986}
}