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Title: Electroanalytical chemistry of complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline

Abstract

Complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline are useful in various electroanalytical methods (extraction voltammetry, direct and indirect variants of potentiometry and coulometry, amperometric and conductometric titration). Most promising at the present time is the use of the electrocatalytic properties of complexes of 2,2'-dipyridyl and 1,10-phenanthroline with transition elements. The combination of specific properties of these catalytic systems with the possibilities of modern polarographic instrumentation allows us to markedly reduce the detection limit and to enhance the selectivity of the techniques for determining a number of metals. Electrochemical methods are irreplaceable in the study of the oxidation-reduction properties of complexes of transition elements with 2,2'-dipyridyl and 1,10-phenanthroline; using them, important characteristic regularities have been established in the field of coordination chemistry of these compounds.

Authors:
; ; ;
Publication Date:
Research Org.:
M. V. Lomonosov Moscow State Univ. (USSR)
OSTI Identifier:
7003715
Resource Type:
Journal Article
Journal Name:
J. Anal. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 42:5; Other Information: Translated from Zh. Anal. Khim.; 42: No. 5, 787-806(May 1987)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COMPLEXES; ION SELECTIVE ELECTRODE ANALYSIS; TITRATION; VOLTAMETRY; PHENANTHROLINES; PYRIDINES; ADSORPTION; ALLOYS; CADMIUM COMPLEXES; ELECTROCHEMISTRY; HALIDES; INDIUM COMPLEXES; INTERFERING ELEMENTS; ION-SELECTIVE ELECTRODES; PHOTOCHEMISTRY; POLAROGRAPHY; QUANTITATIVE CHEMICAL ANALYSIS; RARE EARTH COMPLEXES; RUTHENIUM COMPLEXES; AROMATICS; AZAARENES; AZINES; CHEMICAL ANALYSIS; CHEMISTRY; ELECTRODES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SORPTION; TRANSITION ELEMENT COMPLEXES; 400102* - Chemical & Spectral Procedures

Citation Formats

Prokhorova, G V, Osipova, E A, Agasyan, P K, and Fadeeva, V I. Electroanalytical chemistry of complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline. United States: N. p., 1987. Web.
Prokhorova, G V, Osipova, E A, Agasyan, P K, & Fadeeva, V I. Electroanalytical chemistry of complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline. United States.
Prokhorova, G V, Osipova, E A, Agasyan, P K, and Fadeeva, V I. Tue . "Electroanalytical chemistry of complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline". United States.
@article{osti_7003715,
title = {Electroanalytical chemistry of complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline},
author = {Prokhorova, G V and Osipova, E A and Agasyan, P K and Fadeeva, V I},
abstractNote = {Complex compounds of 2,2'-dipyridyl and 1,10-phenanthroline are useful in various electroanalytical methods (extraction voltammetry, direct and indirect variants of potentiometry and coulometry, amperometric and conductometric titration). Most promising at the present time is the use of the electrocatalytic properties of complexes of 2,2'-dipyridyl and 1,10-phenanthroline with transition elements. The combination of specific properties of these catalytic systems with the possibilities of modern polarographic instrumentation allows us to markedly reduce the detection limit and to enhance the selectivity of the techniques for determining a number of metals. Electrochemical methods are irreplaceable in the study of the oxidation-reduction properties of complexes of transition elements with 2,2'-dipyridyl and 1,10-phenanthroline; using them, important characteristic regularities have been established in the field of coordination chemistry of these compounds.},
doi = {},
url = {https://www.osti.gov/biblio/7003715}, journal = {J. Anal. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 42:5,
place = {United States},
year = {1987},
month = {10}
}