skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Spectroscopy and kinetics of combustion gases at high temperatures

Abstract

This program involves two complementary activities: (1) development and application of cw ring dye laser absorption. methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of radical-molecule and radical-radical reactions relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH[sub 3]; this has necessitated the development of a unique intracavity frequency-doubling system for our cw laser which operates at wavelengths in the range 210--230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions of CH[sub 3] radicals.

Authors:
;
Publication Date:
Research Org.:
Stanford Univ., CA (United States). High Temperature Gasdynamics Lab.
Sponsoring Org.:
USDOE; USDOE, Washington, DC (United States)
OSTI Identifier:
7000934
Report Number(s):
DOE/ER/13857-T3
ON: DE93006892
DOE Contract Number:  
FG03-88ER13857
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COMBUSTION PRODUCTS; SPECTROSCOPY; METHYL RADICALS; ABSORPTION SPECTRA; NITRIC OXIDE; GASES; LASERS; PROGRESS REPORT; RADICALS; SHOCK TUBES; ALKYL RADICALS; CHALCOGENIDES; DOCUMENT TYPES; FLUIDS; NITROGEN COMPOUNDS; NITROGEN OXIDES; OXIDES; OXYGEN COMPOUNDS; SPECTRA; 400800* - Combustion, Pyrolysis, & High-Temperature Chemistry

Citation Formats

Hanson, R K, and Bowman, C T. Spectroscopy and kinetics of combustion gases at high temperatures. United States: N. p., 1992. Web. doi:10.2172/7000934.
Hanson, R K, & Bowman, C T. Spectroscopy and kinetics of combustion gases at high temperatures. United States. https://doi.org/10.2172/7000934
Hanson, R K, and Bowman, C T. Sun . "Spectroscopy and kinetics of combustion gases at high temperatures". United States. https://doi.org/10.2172/7000934. https://www.osti.gov/servlets/purl/7000934.
@article{osti_7000934,
title = {Spectroscopy and kinetics of combustion gases at high temperatures},
author = {Hanson, R K and Bowman, C T},
abstractNote = {This program involves two complementary activities: (1) development and application of cw ring dye laser absorption. methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of radical-molecule and radical-radical reactions relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH[sub 3]; this has necessitated the development of a unique intracavity frequency-doubling system for our cw laser which operates at wavelengths in the range 210--230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions of CH[sub 3] radicals.},
doi = {10.2172/7000934},
url = {https://www.osti.gov/biblio/7000934}, journal = {},
number = ,
volume = ,
place = {United States},
year = {1992},
month = {11}
}