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Title: Experimental pressure-temperature data on three- and four-phase equilibria of fluid, hydrate, and ice phases in the system carbon dioxide-water

Abstract

Pressure-temperature data of three-phase lines, quadruple points, and critical end points of the binary system carbon dioxide-water were taken in a high-pressure view cell at temperatures between 270 and 305 K and pressures up to 7.4 MPa. The phase equilibria involve both fluid (liquid and vapor) phases and solid phases (hydrate and ice). The present results are in good agreement with most data from the literature. Correlations of the experimental data with Clausius-Clapeyron type equations are given. The literature data are reviewed critically in comparison to the correlations. The global phase behavior of the system carbon dioxide-water is discussed and compared to the phase behavior of similar binary systems.

Authors:
; ;  [1]
  1. Univ. Kaiserslautern (Germany). Lehrstuhl fuer Technische Thermodynamik
Publication Date:
OSTI Identifier:
697119
Resource Type:
Journal Article
Journal Name:
Journal of Chemical and Engineering Data
Additional Journal Information:
Journal Volume: 44; Journal Issue: 5; Other Information: PBD: Sep-Oct 1999
Country of Publication:
United States
Language:
English
Subject:
03 NATURAL GAS; GAS HYDRATES; CARBON DIOXIDE; NATURAL GAS; PHASE STUDIES; EQUATIONS OF STATE

Citation Formats

Wendland, M., Hasse, H., and Maurer, G. Experimental pressure-temperature data on three- and four-phase equilibria of fluid, hydrate, and ice phases in the system carbon dioxide-water. United States: N. p., 1999. Web. doi:10.1021/je980208o.
Wendland, M., Hasse, H., & Maurer, G. Experimental pressure-temperature data on three- and four-phase equilibria of fluid, hydrate, and ice phases in the system carbon dioxide-water. United States. doi:10.1021/je980208o.
Wendland, M., Hasse, H., and Maurer, G. Wed . "Experimental pressure-temperature data on three- and four-phase equilibria of fluid, hydrate, and ice phases in the system carbon dioxide-water". United States. doi:10.1021/je980208o.
@article{osti_697119,
title = {Experimental pressure-temperature data on three- and four-phase equilibria of fluid, hydrate, and ice phases in the system carbon dioxide-water},
author = {Wendland, M. and Hasse, H. and Maurer, G.},
abstractNote = {Pressure-temperature data of three-phase lines, quadruple points, and critical end points of the binary system carbon dioxide-water were taken in a high-pressure view cell at temperatures between 270 and 305 K and pressures up to 7.4 MPa. The phase equilibria involve both fluid (liquid and vapor) phases and solid phases (hydrate and ice). The present results are in good agreement with most data from the literature. Correlations of the experimental data with Clausius-Clapeyron type equations are given. The literature data are reviewed critically in comparison to the correlations. The global phase behavior of the system carbon dioxide-water is discussed and compared to the phase behavior of similar binary systems.},
doi = {10.1021/je980208o},
journal = {Journal of Chemical and Engineering Data},
number = 5,
volume = 44,
place = {United States},
year = {1999},
month = {9}
}