Synthesis of arylaliphatic chlorosilanes by alkylation of aromatic compounds by alkenylchlorosilanes

Journal Article · Wed Jan 01 00:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6968313

Bieshev, Y K; Farkhieva, I T; Monakov, Y B; Rafikov, S R

This paper investigates vinyltrichlorosilane (VTCS), (cis-2-butenyl) methyldichlorosilane (BMDCS) and 3-cyclohexenyltrichlorosilane (CHTCS) as ACS. The following compounds were used as alkylation catalysts: The Gustavson complex; EtAlCl/sub 2/ + H/sub 2/O; EtAlCl/sub 2/.HCl; SnCl/sub 4/; TiCl/sub 4/ + CF/sub 3/COOH; BF/sub 3/. O(C/sub 2/H/sub 5/)/sub 2/. In combination with HCl or H/sub 2/O, EtAlCl/sub 2/ is an active catalyst for alkylation of aromatic compounds by alkenylchlorosilanes, and compounds of boron, titanium, and tin are inactive in this reaction.

• Research Organization: Institute of Chemistry, Bashkir Branch, Ufa
• OSTI ID: 6968313
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 34:7,PT.2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM CHLORIDES
CATALYTIC EFFECTS
SILANES
ALKYLATION
SYNTHESIS
BORON COMPOUNDS
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
HYDROCHLORIC ACID
QUANTITY RATIO
TIN COMPOUNDS
TITANIUM COMPOUNDS
WATER
ALUMINIUM COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
SILICON COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties