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Title: Methodology for site-specific, mobility-based cleanup standards for heavy metals in glaciated soils

Abstract

A framework was developed for establishing site-specific, mobility-based cleanup standards for heavy metal contaminated sites that incorporates a detailed soil characterization, laboratory mobility studies, and mathematical modeling. This framework was applied to a chromium contaminated soil from a metal finishing facility. A series of column leaching experiments were conducted at two different flow rates and influent pHs. A mathematical model was used to describe the fate, speciation, and transport of heavy metals in porous media. In this model, dissolved heavy metals interact with oxide coatings and soil organic matter on the outer surfaces of soil grains via surface complexation reactions. In addition, dissolved heavy metals diffuse into the soil matrix and react with intragranular reactive sites. Model simulations were performed for chromium to determine apparent mass transfer coefficients. A long-term simulation of the unsaturated zone at the site was performed to estimate cleanup levels for chromium under natural attenuation conditions. Applying this framework for the site-specific, mobility-based determination of cleanup levels provides a solution to the problem of estimating a practical cleanup goal.

Authors:
; ;  [1]
  1. Univ. of Connecticut, Storrs, CT (United States)
Publication Date:
OSTI Identifier:
696766
Resource Type:
Journal Article
Journal Name:
Environmental Science and Technology
Additional Journal Information:
Journal Volume: 33; Journal Issue: 17; Other Information: PBD: 1 Sep 1999
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 29 ENERGY PLANNING AND POLICY; REMEDIAL ACTION; SOILS; MATHEMATICAL MODELS; CHROMIUM; ENVIRONMENTAL TRANSPORT; STANDARDS

Citation Formats

Nikolaidis, N.P., Hellerich, L.A., and Lackovic, J.A. Methodology for site-specific, mobility-based cleanup standards for heavy metals in glaciated soils. United States: N. p., 1999. Web. doi:10.1021/es990230h.
Nikolaidis, N.P., Hellerich, L.A., & Lackovic, J.A. Methodology for site-specific, mobility-based cleanup standards for heavy metals in glaciated soils. United States. doi:10.1021/es990230h.
Nikolaidis, N.P., Hellerich, L.A., and Lackovic, J.A. Wed . "Methodology for site-specific, mobility-based cleanup standards for heavy metals in glaciated soils". United States. doi:10.1021/es990230h.
@article{osti_696766,
title = {Methodology for site-specific, mobility-based cleanup standards for heavy metals in glaciated soils},
author = {Nikolaidis, N.P. and Hellerich, L.A. and Lackovic, J.A.},
abstractNote = {A framework was developed for establishing site-specific, mobility-based cleanup standards for heavy metal contaminated sites that incorporates a detailed soil characterization, laboratory mobility studies, and mathematical modeling. This framework was applied to a chromium contaminated soil from a metal finishing facility. A series of column leaching experiments were conducted at two different flow rates and influent pHs. A mathematical model was used to describe the fate, speciation, and transport of heavy metals in porous media. In this model, dissolved heavy metals interact with oxide coatings and soil organic matter on the outer surfaces of soil grains via surface complexation reactions. In addition, dissolved heavy metals diffuse into the soil matrix and react with intragranular reactive sites. Model simulations were performed for chromium to determine apparent mass transfer coefficients. A long-term simulation of the unsaturated zone at the site was performed to estimate cleanup levels for chromium under natural attenuation conditions. Applying this framework for the site-specific, mobility-based determination of cleanup levels provides a solution to the problem of estimating a practical cleanup goal.},
doi = {10.1021/es990230h},
journal = {Environmental Science and Technology},
number = 17,
volume = 33,
place = {United States},
year = {1999},
month = {9}
}