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Title: Self-diffusion processes in nuclear carbonitrides UC/sub x/N/sub 1-x/ and (U,Pu)C/sub 0/ /sub 8/N/sub 0/ /sub 2/

Journal Article · · Nucl. Sci. Eng.; (United States)
OSTI ID:6940681

The self-diffusion of /sup 14/C and /sup 233/U in four different uranium carbonitrides, UC/sub x/N/sub 1-x/ with x = 0.67, 0.26, 0.24, and 0.18, and the diffusion of /sup 238/Pu in two sets of (U,Pu)C/sub 0/./sub 8/N/sub 0/./sub 2/ were measured. Replacing carbon by nitrogen decreased self-diffusion rates in both metal and non-metal lattices. The decrease was not linear with x; rather, a change in mechanism or bonding at around x approximately equal to 0.5 was indicated. The data are of importance for both fabrication and reactor operation of carbonitrides.

Research Organization:
Inst. for Transuranium Elements, Karlsruhe, Ger.
OSTI ID:
6940681
Journal Information:
Nucl. Sci. Eng.; (United States), Vol. 66:3
Country of Publication:
United States
Language:
English