skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ultraviolet laser photochemistry of halogenated methanes

Abstract

The uv laser photochemistry of CF/sub 2/Br/sub 2/, CCl/sub 4/, CCl/sub 3/F, and CCl/sub 2/F/sub 2/ was studied. The emission spectra and dynamics of the halogenated alkyl radicals formed from the excimer laser photolysis of these compounds are reported. Possible mechanistic routes are also examined. Some results are given from studies on the kinetics of CCl, CCl/sub 2/, and CClF ground state radicals with various reactants.

Authors:
; ;
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
OSTI Identifier:
6904023
Report Number(s):
LA-UR-80-2798; CONF-801139-1
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Conference
Resource Relation:
Conference: Electro-optics/laser conference, Boston, MA, USA, 19 Nov 1980
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALKYL RADICALS; CHEMICAL REACTION KINETICS; CARBON TETRACHLORIDE; EMISSION SPECTRA; PHOTOLYSIS; CHLORINATED ALIPHATIC HYDROCARBONS; FLUORINATED ALIPHATIC HYDROCARBONS; FLUOROFORM; LASERS; CHEMICAL REACTIONS; DECOMPOSITION; HALOGENATED ALIPHATIC HYDROCARBONS; KINETICS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHOTOCHEMICAL REACTIONS; RADICALS; REACTION KINETICS; SPECTRA; 400500* - Photochemistry

Citation Formats

Wampler, F B, Tiee, J J, and Oldenborg, R C. Ultraviolet laser photochemistry of halogenated methanes. United States: N. p., 1980. Web.
Wampler, F B, Tiee, J J, & Oldenborg, R C. Ultraviolet laser photochemistry of halogenated methanes. United States.
Wampler, F B, Tiee, J J, and Oldenborg, R C. 1980. "Ultraviolet laser photochemistry of halogenated methanes". United States. https://www.osti.gov/servlets/purl/6904023.
@article{osti_6904023,
title = {Ultraviolet laser photochemistry of halogenated methanes},
author = {Wampler, F B and Tiee, J J and Oldenborg, R C},
abstractNote = {The uv laser photochemistry of CF/sub 2/Br/sub 2/, CCl/sub 4/, CCl/sub 3/F, and CCl/sub 2/F/sub 2/ was studied. The emission spectra and dynamics of the halogenated alkyl radicals formed from the excimer laser photolysis of these compounds are reported. Possible mechanistic routes are also examined. Some results are given from studies on the kinetics of CCl, CCl/sub 2/, and CClF ground state radicals with various reactants.},
doi = {},
url = {https://www.osti.gov/biblio/6904023}, journal = {},
number = ,
volume = ,
place = {United States},
year = {1980},
month = {1}
}

Conference:
Other availability
Please see Document Availability for additional information on obtaining the full-text document. Library patrons may search WorldCat to identify libraries that hold this conference proceeding.

Save / Share: