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Title: Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions. III. Electronic and catalytic properties of nickel catalysts

Abstract

Various nickel catalysts (nickle-boride, nickel-phosphide, Raney-nickel, Urushibara-nickel, and decomposed-nickel) were investigated to examine the relationships between catalytic and electronic properties of nickel catalysts modified by component elements (boron, phosphorus, aluminum, and zinc) in the catalysts. Based on the x-ray photoelectron spectroscopic results, a parameter ..delta..q was tentatively proposed to characterize the electronic properties of the catalysts. The specific activity (activity per surface area of nickel metal) for hydrogenation reaction, the adsorption equilibrium constant of acetophenone, the resistivity against poisoning, and the characteristic selectivities in hydrogenation of 1,2-butylene oxide were found to be summarized in terms of the parameter ..delta..q. It is suggested that a useful parameter to reflect the electronic properties of the nickel catalysts.

Authors:
; ; ;
Publication Date:
Research Org.:
Osaka Univ., Japan
OSTI Identifier:
6810557
Resource Type:
Journal Article
Journal Name:
J. Catal.; (United States)
Additional Journal Information:
Journal Volume: 64:2
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; BORON; CATALYTIC EFFECTS; POISONING; SURFACE PROPERTIES; BUTENES; HYDROGENATION; NICKEL; ORGANIC OXYGEN COMPOUNDS; PHOSPHORUS; ALUMINIUM; ZINC; EXPERIMENTAL DATA; METHANATION; ALKENES; CHEMICAL REACTIONS; DATA; ELEMENTS; HYDROCARBONS; INFORMATION; METALS; NONMETALS; NUMERICAL DATA; ORGANIC COMPOUNDS; SEMIMETALS; TRANSITION ELEMENTS; 090121* - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)

Citation Formats

Okamoto, Y, Nitta, Y, Imanaka, T, and Teranishi, S. Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions. III. Electronic and catalytic properties of nickel catalysts. United States: N. p., 1980. Web. doi:10.1016/0021-9517(80)90512-6.
Okamoto, Y, Nitta, Y, Imanaka, T, & Teranishi, S. Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions. III. Electronic and catalytic properties of nickel catalysts. United States. https://doi.org/10.1016/0021-9517(80)90512-6
Okamoto, Y, Nitta, Y, Imanaka, T, and Teranishi, S. 1980. "Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions. III. Electronic and catalytic properties of nickel catalysts". United States. https://doi.org/10.1016/0021-9517(80)90512-6.
@article{osti_6810557,
title = {Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions. III. Electronic and catalytic properties of nickel catalysts},
author = {Okamoto, Y and Nitta, Y and Imanaka, T and Teranishi, S},
abstractNote = {Various nickel catalysts (nickle-boride, nickel-phosphide, Raney-nickel, Urushibara-nickel, and decomposed-nickel) were investigated to examine the relationships between catalytic and electronic properties of nickel catalysts modified by component elements (boron, phosphorus, aluminum, and zinc) in the catalysts. Based on the x-ray photoelectron spectroscopic results, a parameter ..delta..q was tentatively proposed to characterize the electronic properties of the catalysts. The specific activity (activity per surface area of nickel metal) for hydrogenation reaction, the adsorption equilibrium constant of acetophenone, the resistivity against poisoning, and the characteristic selectivities in hydrogenation of 1,2-butylene oxide were found to be summarized in terms of the parameter ..delta..q. It is suggested that a useful parameter to reflect the electronic properties of the nickel catalysts.},
doi = {10.1016/0021-9517(80)90512-6},
url = {https://www.osti.gov/biblio/6810557}, journal = {J. Catal.; (United States)},
number = ,
volume = 64:2,
place = {United States},
year = {Fri Aug 01 00:00:00 EDT 1980},
month = {Fri Aug 01 00:00:00 EDT 1980}
}