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Title: Solid oxide fuel cells with doped lanthanum gallate electrolyte and LaSrCoO{sub 3} cathode, and Ni-samaria-doped ceria cermet anode

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1391882· OSTI ID:680013
; ;  [1]; ; ;  [2];  [3]
  1. Japan Fine Ceramics Center, Nagoya (Japan)
  2. Kansai Electric Power Co., Inc., Hyogo (Japan)
  3. Kanden Kakou Co., Ltd., Hyogo (Japan)

The electrode performance of a single solid-oxide fuel cell (SOFC) was evaluated using a 500 {micro}m thick La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}O{sub 0.3} (LSGM) as the electrolyte membrane. A doped lanthanum cobaltite, La{sub 0.6}Sr{sub 0.4}CoO{sub 3{minus}{delta}} was selected as the cathode material, and a samaria-doped ceria-NiO composite powder was used as the anode material. The spray-pyrolysis method was applied for synthesis of the starting powders of the cathode and anode. In this study, different microstructures of the cathode were obtained by varying the sintering temperature from 950 to 1200 C. High power density (the maximum power density of the cell was about 425 mW/cm{sup 2}, which is 95% of the theoretical value) of the solid oxide fuel cell at 800 C was achieved. The cell performance showed that, with a proper choice of electrode materials with optimized microstructure and LSGM as the electrolyte, a SOFC operating at temperatures T{sub op} {le} 800 is a realistic goal.

OSTI ID:
680013
Journal Information:
Journal of the Electrochemical Society, Vol. 146, Issue 6; Other Information: PBD: Jun 1999
Country of Publication:
United States
Language:
English