Organic constituents in process water from the in-situ retorting of oil from oil-shale kerogen
Capillary-column gas-chromatography/mass-spectrometry (GC/MS) was performed on the acid, base, and neutral fractions of liquid- and particulate-phase methylene chloride extracts of a composite sample of raw process water collected from separator Tank 6 by the Laramie Energy Technology Center. Of the 160 extractable and chromatographable organic compounds tentatively identified, the following compound classes were found (listed in decreasing order of abundance): quinolines and lower fatty acids, aminoindoles, neutral oxygenated heterocyclics, pyridines, pyrroles, pyrazoles, phenols, and alkanes. Noticeably absent or in low concentration were alkyl benzenes and alkenes. Assuming 100% extraction efficiency, these organics constitute approximately 0.035% of the retort water; approximately 50% of this amount is represented by the quinolines, fatty acids, aminoindoles, and oxygenated heterocyclics. The following differences were noted in the composition of the particulate and liquid extracts of the neutral and base fractions, respectively: (1) alkanes are a major portion of the particulates, whereas oxygenated hereocyclics are most prominent in the liquid; and (2) aminoindoles are only a minor portion of the particulates, but are prominent in the liquid phase. The concentration of a compound occurring in both the liquid and particulate extracts is approximately 40 to 100 times higher in the liquid than in the particulate extract.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-31-109-ENG-38
- OSTI ID:
- 6783994
- Report Number(s):
- ANL/PAG-5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
IN-SITU RETORTING
WASTE WATER
OIL SHALES
OXY MODIFIED IN-SITU PROCESS
ALKANES
HETEROCYCLIC OXYGEN COMPOUNDS
LIQUIDS
OIL SHALE DEPOSITS
ORGANIC COMPOUNDS
PARTICLES
PHENOLS
PYRAZOLES
PYRIDINES
QUINOLINES
AROMATICS
AZINES
AZOLES
BITUMINOUS MATERIALS
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
DECOMPOSITION
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUELS
GEOLOGIC DEPOSITS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
IN-SITU PROCESSING
LIQUID WASTES
MATERIALS
MINERAL RESOURCES
MODIFIED IN-SITU PROCESSES
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
PROCESSING
RESOURCES
RETORTING
WASTES
WATER
040401* - Oil Shales & Tar Sands- In Situ Methods
True & Modified
040900 - Oil Shales & Tar Sands- Waste management
041000 - Oil Shales & Tar Sands- Environmental Aspects