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Title: FeTi methanation catalyst

Abstract

The intermetallic compound FeTi was found to catalyze the reduction of CO and CO/sub 2/ to methane by hydrogen. CO reduction yielded traces of ethane as did CO/sub 2/, in addition, CO/sub 2/ reduction yielded small amounts of methanol. The appearance of CH/sub 4/ was linear with time for both CO and CO/sub 2/ and the rate of CO/sub 2/ reduction was faster than that observed for CO. The product distribution and rate data lend support to and will be discussed in terms of the newly proposed oxide theory for Fischer-Tropsch and related synthesis.

Authors:
; ;
Publication Date:
Research Org.:
Brookhaven National Lab., Upton, NY (USA)
Sponsoring Org.:
USDOE
OSTI Identifier:
6701984
Report Number(s):
BNL-24477; CONF-780902-1
DOE Contract Number:  
EY-76-C-02-0016
Resource Type:
Conference
Resource Relation:
Conference: American Chemical Society meeting, Miami, FL, USA, 10 Sep 1978
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; CARBON DIOXIDE; METHANATION; CARBON MONOXIDE; IRON ALLOYS; CATALYTIC EFFECTS; TITANIUM ALLOYS; FISCHER-TROPSCH SYNTHESIS; INTERMETALLIC COMPOUNDS; METHANE; SYNTHESIS; ALKANES; ALLOYS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; CRYOGENIC FLUIDS; FLUIDS; HYDROCARBONS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; 090121* - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)

Citation Formats

Lynch, J R, Spaulding, L D, and Sapienza, R S. FeTi methanation catalyst. United States: N. p., 1978. Web.
Lynch, J R, Spaulding, L D, & Sapienza, R S. FeTi methanation catalyst. United States.
Lynch, J R, Spaulding, L D, and Sapienza, R S. Thu . "FeTi methanation catalyst". United States. https://www.osti.gov/servlets/purl/6701984.
@article{osti_6701984,
title = {FeTi methanation catalyst},
author = {Lynch, J R and Spaulding, L D and Sapienza, R S},
abstractNote = {The intermetallic compound FeTi was found to catalyze the reduction of CO and CO/sub 2/ to methane by hydrogen. CO reduction yielded traces of ethane as did CO/sub 2/, in addition, CO/sub 2/ reduction yielded small amounts of methanol. The appearance of CH/sub 4/ was linear with time for both CO and CO/sub 2/ and the rate of CO/sub 2/ reduction was faster than that observed for CO. The product distribution and rate data lend support to and will be discussed in terms of the newly proposed oxide theory for Fischer-Tropsch and related synthesis.},
doi = {},
url = {https://www.osti.gov/biblio/6701984}, journal = {},
number = ,
volume = ,
place = {United States},
year = {1978},
month = {6}
}

Conference:
Other availability
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