Thermochemical and thermophysical properties of organic compounds derived from fossil substances: Thermodynamic studies related to the hydrogenation of anthracene. [9,10-dihydroanthracene, phenyl-o-tolylmethane, and 1,2,3,4-tetrahydroanthracene]
Technical Report
·
OSTI ID:6676032
Experimental details of vapor pressure, enthalpy of combustion, and condensed-phase heat capacity studies are reported for 9,10-dihydroanthracene, phenyl-o-tolylmethane, and 1,2,3,4-tetrahydroanthracene. The results are combined to produce values of the Gibbs energy of formation in the ideal-gas state at selected temperatures for each molecule. The derived Gibbs energies are used in equilibria calculations that provide insights into the roles of temperature and hydrogen pressure in the control of product slate in the hydrogenation of anthracene. 38 refs., 8 figs., 19 tabs.
- Research Organization:
- National Inst. for Petroleum and Energy Research, Bartlesville, OK (USA)
- DOE Contract Number:
- FC22-83FE60149
- OSTI ID:
- 6676032
- Report Number(s):
- NIPER-239; ON: DE87001235
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ANTHRACENE
HYDROGENATION
AROMATICS
COMBUSTION HEAT
FREE ENTHALPY
SPECIFIC HEAT
VAPOR PRESSURE
CONDENSED AROMATICS
CALCULATION METHODS
CALORIMETRY
COAL LIQUIDS
EQUILIBRIUM
EXPERIMENTAL DATA
HYDROGEN
PARTIAL PRESSURE
STRUCTURAL MODELS
THERMODYNAMIC PROPERTIES
CHEMICAL REACTIONS
DATA
ELEMENTS
ENERGY
ENTHALPY
FLUIDS
HEAT
HYDROCARBONS
INFORMATION
LIQUIDS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
010405* - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ANTHRACENE
HYDROGENATION
AROMATICS
COMBUSTION HEAT
FREE ENTHALPY
SPECIFIC HEAT
VAPOR PRESSURE
CONDENSED AROMATICS
CALCULATION METHODS
CALORIMETRY
COAL LIQUIDS
EQUILIBRIUM
EXPERIMENTAL DATA
HYDROGEN
PARTIAL PRESSURE
STRUCTURAL MODELS
THERMODYNAMIC PROPERTIES
CHEMICAL REACTIONS
DATA
ELEMENTS
ENERGY
ENTHALPY
FLUIDS
HEAT
HYDROCARBONS
INFORMATION
LIQUIDS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
010405* - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties